Alcohols, carboxylic acids and polymers
By the end of this chapter you will be able to
- Name the first alcohols and state the functional group
- Compare fermentation and hydration for making ethanol
- Write word equations for the reactions of a carboxylic acid
- Draw the repeat unit of an addition polymer from its monomer
- Compare thermosoftening and thermosetting polymers, and biodegradable and non-biodegradable polymers
You should already know
- Alkenes and the double bond (Chapter 15)
- Balancing equations and Mr (Chapters 7 and 8)
- Acids and salts (Chapter 10)
Where this leads
- Crude oil as the source of monomers (Chapter 15)
- Sustainability and recycling (Chapter 19)
GCSE Chemistry. Content follows the GCSE (9-1) subject content for England (Edexcel and AQA). Content references: Describe the alcohols as a homologous series with the -OH group (general formula CnH2n+1OH), Compare making ethanol by fermentation and by hydration of ethene, Describe carboxylic acids (-COOH) and their reactions with carbonates, alkalis and metals, [H] Describe esters, and the reaction of an alcohol with a carboxylic acid, Draw the repeat unit of addition polymers, and compare thermosoftening and thermosetting polymers, including [H] condensation polymers.
Exercise P Do you remember?
Method. Alkenes are CnH2n; n = 2.
- Count. H = 2 x 2 = 4.H4
- Write the answer. C2H4
Check. Ethene. ✓
Method. Add the Ar values.
- Add. 12 + 2 x 16 = 44.44
- Write the answer. 44
Check. Chapter 7. ✓
Method. Recall the products.
- Recall. Carbonates release carbon dioxide.carbon dioxide
- Write the answer. carbon dioxide
Check. Chapter 10. ✓
Method. Multiply, then add.
- Multiply. 2 x 46 = 92 and 2 x 44 = 88.92 and 88
- Add. 92 + 88 = 180.180
- Write the answer. 180
Check. 180 is the Mr of glucose. ✓
Method. Recall the group.
- Recall. Sodium is in group 1.1
- Write the answer. 1
Check. Chapter 2. ✓
Alcohols and making ethanol
The alcohols are a homologous series with the -OH functional group. Their general formula is CnH2n+1OH. The first alcohols are methanol (CH3OH), ethanol (C2H5OH), propanol and butanol. Ethanol is used as a solvent, a fuel and in drinks.
Ethanol is made in two ways. In fermentation, yeast converts sugar into ethanol and carbon dioxide without air (anaerobically): C6H12O6 -> 2C2H5OH + 2CO2. In hydration, ethene from crude oil reacts with steam: C2H4 + H2O -> C2H5OH.
| Method | Starting material | Conditions | Notes |
|---|---|---|---|
| fermentation | sugar (glucose) and yeast | anaerobic, about 30 degrees C | renewable; slow; uses an impure mixture |
| hydration of ethene | ethene and steam | a phosphoric acid catalyst, about 300 degrees C, high pressure | fast and pure; uses crude oil |
Key ideas
- Alcohols have the -OH functional group and the general formula CnH2n+1OH.
- Fermentation: sugar and yeast, anaerobic, about 30 degrees C; renewable but slow.
- Hydration: ethene and steam, a phosphoric acid catalyst, high temperature and pressure; fast and pure.
- Ethanol is a solvent, a fuel and the alcohol in drinks.
Method. Recall the general formula.
- Recall. Alcohols have the general formula CnH2n+1OH.CnH2n+1OH
- Check. For ethanol, n = 2: C2H5OH, which fits.C2H5OH
- Write the answer. CnH2n+1OH
Check. The -OH group is the functional group. ✓
Method. Recall the functional group.
- Recall. Alcohols contain the -OH group.-OH
- Decide. So the functional group is -OH.-OH
- Write the answer. -OH
Check. Ethanol is C2H5OH. ✓
Method. Think about the conditions.
- Look. Fermentation is anaerobic: it needs no air.anaerobic
- Conclude. A closed vessel keeps air out, so the process is anaerobic.keeps air out
- Write the answer. to keep air out, so the fermentation is anaerobic
Check. The yeast works best at about 30 degrees C. ✓
Watch out
Watch out: fermentation is slow and makes an impure product. Hydration uses crude oil and is fast, but it is not renewable. Compare them in terms of the feedstock, speed and purity.
Exam tip
Exam tip. Compare the two methods using a table: starting material, conditions, speed, purity and whether it is renewable.
Exercise 16A Alcohols and making ethanol
Method. Recall the alcohols.
- Recall. The simplest alcohol with two carbons is ethanol.ethanol
- Write the answer. ethanol
Check. Ethanol is C2H5OH. ✓
Method. Recall the group.
- Recall. The -OH group is the functional group of alcohols.-OH
- Write the answer. -OH
Check. It is a hydroxyl group. ✓
Method. One carbon and an -OH group.
- Build. CH3 + OH.CH3OH
- Write the answer. CH3OH
Check. Methanol is the first alcohol. ✓
Method. Two carbons, five hydrogens, and an -OH group.
- Build. C2H5 + OH.C2H5OH
- Write the answer. C2H5OH
Check. Ethanol has Mr 46. ✓
Method. Recall the starting material.
- Recall. Yeast converts sugar into ethanol and carbon dioxide.sugar
- Write the answer. sugar
Check. Glucose is the sugar used. ✓
Method. Recall the organism.
- Recall. Yeast is used in fermentation.yeast
- Write the answer. yeast
Check. Yeast is a fungus. ✓
Method. Recall the condition.
- Recall. The yeast works at about 30 degrees C.30
- Write the answer. 30
Check. Higher temperatures kill the yeast. ✓
Method. Recall the catalyst.
- Recall. Phosphoric acid is used as the catalyst.phosphoric acid
- Write the answer. phosphoric acid
Check. Hydration needs high temperature and pressure. ✓
Method. Add the Ar values.
- Add. 2 x 12 + 6 x 1 + 16 = 46.46
- Write the answer. 46
Check. C2H6O: 24 + 6 + 16 = 46. ✓
Method. Add the products and compare.
- Products. 92 + 88 = 180 g.180
- Decide. The products total 180 g, equal to the glucose, so mass is conserved.yes
- Write the answer. yes
Check. Mass is conserved in every chemical reaction. ✓
Method. Ethene and steam add to form ethanol.
- Product. C2H4 + H2O -> C2H5OH.ethanol
- Write the answer. ethanol
Check. The product is ethanol. ✓
Method. Think about the source.
- Source. The sugar comes from crops that can be grown again.grown again
- Conclude. So the process uses a renewable resource.renewable
- Write the answer. Accept any sentence that says the sugar comes from plants, which can be grown again.
Check. Crude oil is not renewable. ✓
Method. Compare the two methods.
- Fermentation. Fermentation uses renewable sugar but is slow.slow
- Hydration. Hydration is fast but uses crude oil, which is not renewable.fast
- Write the answer. Accept any answer that says fermentation uses renewable sugar but is slow, while hydration is fast and uses crude oil.
Check. Both methods give ethanol. ✓
Carboxylic acids and esters [H]
Carboxylic acids contain the -COOH functional group. Ethanoic acid (CH3COOH) is the carboxylic acid in vinegar. Carboxylic acids are weak acids, and they react like other acids: with carbonates to form a salt, water and carbon dioxide; with alkalis to form a salt and water; and with some metals to form a salt and hydrogen. The salt of ethanoic acid is an ethanoate.
[H] Higher tier only. An alcohol and a carboxylic acid react, with an acid catalyst, to form an ester and water. For example, ethanol and ethanoic acid give ethyl ethanoate: C2H5OH + CH3COOH -> CH3COOC2H5 + H2O. Esters have fruity smells and are used in flavourings and perfumes.
Key ideas
- Carboxylic acids have the -COOH group.
- Carboxylic acid + carbonate -> salt + water + carbon dioxide.
- Carboxylic acid + alkali -> salt + water.
- [H] Alcohol + carboxylic acid -> ester + water (acid catalyst).
Method. Carbonates give a salt, water and carbon dioxide.
- Salt. The salt is sodium ethanoate.sodium ethanoate
- Others. Water and carbon dioxide are also made.water and carbon dioxide
- Write the answer. sodium ethanoate, water and carbon dioxide
Check. The reaction is like the one in Chapter 10. ✓
Method. Name the salt from the metal and the acid part.
- Metal. The metal is sodium.sodium
- Acid part. Ethanoic acid gives ethanoate.ethanoate
- Salt. So the salt is sodium ethanoate.sodium ethanoate
- Write the answer. sodium ethanoate
Check. Water is also formed. ✓
Method. Name the ester from the alcohol and the acid.
- Alcohol part. The alcohol is ethanol, giving the ethyl group.ethyl
- Acid part. The acid is ethanoic acid, giving ethanoate.ethanoate
- Ester. So the ester is ethyl ethanoate.ethyl ethanoate
- Write the answer. ethyl ethanoate
Check. It has a fruity smell. ✓
Watch out
Watch out: carboxylic acids are weak acids, so they are not as strong as hydrochloric acid, but they still react with carbonates, alkalis and metals like other acids.
Exam tip
Exam tip. Name a salt of a carboxylic acid with “-oate”: ethanoic acid gives ethanoates.
Exercise 16B Carboxylic acids and esters [H]
Method. Recall the group.
- Recall. The carboxylic acid group is -COOH.-COOH
- Write the answer. -COOH
Check. Vinegar contains ethanoic acid. ✓
Method. Recall the formula.
- Recall. Ethanoic acid is CH3COOH.CH3COOH
- Write the answer. CH3COOH
Check. Two carbons, four hydrogens, two oxygens. ✓
Method. Recall the gas.
- Recall. Carbonates release carbon dioxide.carbon dioxide
- Write the answer. carbon dioxide
Check. Carbon dioxide bubbles are seen. ✓
Method. Metal, then the acid part.
- Name. Sodium and ethanoate give sodium ethanoate.sodium ethanoate
- Write the answer. sodium ethanoate
Check. Water is also made. ✓
Method. Recall the products of neutralisation.
- Recall. Neutralisation gives a salt and water.water
- Write the answer. water
Check. The same pattern as acids and alkalis. ✓
Method. Recall the strength.
- Recall. Ethanoic acid is a weak acid.weak
- Write the answer. weak
Check. Hydrochloric acid is strong. ✓
Method. Recall the ending.
- Recall. Salts of ethanoic acid are ethanoates.ethanoate
- Write the answer. ethanoate
Check. Sodium ethanoate is one example. ✓
Method. The alcohol gives the first part of the name.
- Alcohol. Methanol gives the methyl group.methyl
- Acid. Ethanoic acid gives ethanoate.ethanoate
- Write the answer. methyl ethanoate
Check. The same pattern as ethyl ethanoate. ✓
Method. Esterification forms water as well.
- Products. An ester and water are formed.ester and water
- Write the answer. ester and water
Check. The reaction needs an acid catalyst. ✓
Method. Check the equation.
- Look. C2H5OH + CH3COOH -> CH3COOC2H5 + H2O.H2O
- Decide. So water is the other product.yes
- Write the answer. yes
Check. The mass of the reactants is 46 + 60 = 106 g; ester 88 g and water 18 g. ✓
Method. Think about the ions.
- Ions. Carboxylic acids release H+ ions in water.H+ ions
- Conclude. So they show the properties of acids, such as reacting with carbonates.properties
- Write the answer. Accept any sentence that says it releases H+ ions in water, like other acids.
Check. It is a weak acid, but it is still an acid. ✓
Method. Think about the uses.
- Uses. Esters are used in flavourings and perfumes.flavourings
- Conclude. Their smells are pleasant, which is why they are used.pleasant smell
- Write the answer. Accept any sentence that says esters are used in flavourings and perfumes because of their smell.
Check. Esters are made from alcohols and acids. ✓
Addition polymers and their repeat units
In addition polymerisation, many small monomers with a C=C double bond join to form a long chain, with no other product. The repeat unit is the part of the chain that is repeated; it is written in brackets with n for a large number. Poly(ethene) is made from ethene; poly(propene) from propene; and PVC (poly(chloroethene)) from chloroethene.
| Monomer | Formula | Repeat unit of the polymer | Polymer |
|---|---|---|---|
| ethene | CH2=CH2 | -CH2-CH2- | poly(ethene) |
| propene | CH2=CHCH3 | -CH(CH3)-CH2- | poly(propene) |
| chloroethene | CH2=CHCl | -CH2-CHCl- | PVC (poly(chloroethene)) |
Key ideas
- Addition polymers form from alkene monomers, with no other product.
- The repeat unit has the same atoms as the monomer, with the double bond opened.
- PVC: chloroethene monomer; repeat unit has a Cl on alternate carbons.
- Write the repeat unit with brackets and n outside.
Method. Open the double bond and join the monomers.
- Open. The C=C becomes C-C, with each carbon bonded to the next monomer.C-C
- Repeat. The repeat unit is the CH2CH2 unit.CH2-CH2
- Write the answer. -CH2-CH2-
Check. Each carbon keeps two hydrogens in the repeat unit. ✓
Method. Keep the Cl on one carbon of each unit.
- Open. The double bond opens; each carbon keeps one bond to the next unit.open
- Repeat. The unit has CH2 and CHCl.CH2-CHCl
- Write the answer. -CH2-CHCl-
Check. Chlorine is kept in every repeat unit. ✓
Method. Keep the methyl group on the same carbon.
- Open. The double bond opens and the CH3 stays on the middle carbon.CH3 stays
- Repeat. The unit is -CH(CH3)-CH2-.CH(CH3)-CH2
- Write the answer. -CH(CH3)-CH2-
Check. Poly(propene) has a methyl group on each unit. ✓
Watch out
Watch out: the repeat unit is not the same as the monomer. The double bond is opened, and the carbons are joined to the neighbouring units.
Exam tip
Exam tip. Draw the monomer, open the double bond, and write the repeat unit in brackets with n.
Exercise 16C Addition polymers and their repeat units
Method. Recall the process.
- Recall. Joining monomers into a polymer is polymerisation.polymerisation
- Write the answer. polymerisation
Check. Addition polymerisation is one type. ✓
Method. Recall the name.
- Recall. The small molecules are monomers.monomers
- Write the answer. monomers
Check. Ethene is a monomer. ✓
Method. Recall the monomer.
- Recall. Poly(ethene) is made from ethene.ethene
- Write the answer. ethene
Check. Ethene is C2H4. ✓
Method. Recall the monomer.
- Recall. PVC is made from chloroethene.chloroethene
- Write the answer. chloroethene
Check. Chloroethene is CH2=CHCl. ✓
Method. Recall the feature.
- Recall. The monomer must have a C=C double bond.double bond
- Write the answer. a carbon-carbon double bond
Check. The double bond opens to join the units. ✓
Method. Count the carbons in -CH2-CH2-.
- Count. The repeat unit has two CH2 groups, so 2 carbons.2
- Write the answer. 2
Check. Ethene has 2 carbons. ✓
Method. Recall the repeat unit.
- Recall. The repeat unit is -CH2-CH2-.-CH2-CH2-
- Write the answer. -CH2-CH2-
Check. Two carbons and four hydrogens. ✓
Method. Recall the repeat unit.
- Recall. The repeat unit of PVC is -CH2-CHCl-.-CH2-CHCl-
- Write the answer. -CH2-CHCl-
Check. Chlorine on one of the two carbons. ✓
Method. Recall the process.
- Recall. The monomers join with no other product.no
- Write the answer. no
Check. This is the feature of addition. ✓
Method. Count the atoms.
- Count. Two carbons, three hydrogens and one chlorine.C2H3Cl
- Write the answer. C2H3Cl
Check. Mr = 62.5. ✓
Method. Open the unit back up to a double bond.
- Look. The unit has three carbons and six hydrogens.C3H6
- Name. The monomer with C3H6 and a double bond is propene.propene
- Write the answer. propene
Check. Propene is CH2=CHCH3. ✓
Method. Think about the atoms.
- Atoms. In addition, all the atoms of the monomer stay in the polymer.all atoms stay
- Conclude. So nothing else is formed.nothing else
- Write the answer. Accept any sentence that says the double bond opens and the monomers join with no atoms lost.
Check. Condensation polymers do give a small molecule. ✓
Condensation polymers [H] and types of polymer
Thermosoftening polymers have long, separate chains. When heated, they soften, and they can be remoulded. Thermosetting polymers have cross-linked chains, with strong bonds between them. When heated, they do not soften; they decompose or char. Thermosetting polymers are used for electrical plugs and kitchen utensils.
[H] Higher tier only. Condensation polymers form when monomers with two functional groups join, with a small molecule (such as water) lost each time. Polyesters and nylon are examples. The repeat unit has the atoms of both monomers minus the small molecule.
| Property | Thermosoftening polymer | Thermosetting polymer |
|---|---|---|
| when heated | softens and can be remoulded | does not soften; it decomposes or chars |
| structure | long chains, not cross-linked | cross-linked chains, strong bonds between them |
| examples | poly(ethene), PVC | melamine, bakelite (epoxy resins) |
Key ideas
- Thermosoftening: long chains, soften when heated, can be remoulded.
- Thermosetting: cross-linked chains, do not soften, decompose or char.
- [H] Condensation polymers lose a small molecule (for example water) as they form.
- Polyesters and nylon are condensation polymers.
Method. Recall the property.
- Recall. Thermosetting polymers do not soften when heated.no
- Decide. So they cannot be remoulded.cannot remould
- Write the answer. no
Check. Thermosoftening polymers can be remoulded. ✓
Method. Think about the structure.
- Look. Thermosetting polymers have cross-links between the chains.cross-links
- Conclude. The strong cross-links hold the chains in place when heated.hold in place
- Write the answer. the cross-links hold the chains in place
Check. Thermosoftening chains can slide past each other. ✓
Method. Recall the byproduct.
- Recall. In a condensation reaction, a small molecule such as water is lost.water
- Decide. So the answer is water.water
- Write the answer. water
Check. The polymer has the atoms of both monomers minus the water. ✓
Watch out
Watch out: do not call a thermosetting polymer “thermosoftening”. The difference is whether the polymer softens when it is heated.
Exam tip
Exam tip. Link the property to the structure: cross-links for thermosetting, separate chains for thermosoftening.
Exercise 16D Condensation polymers [H] and types of polymer
Method. Recall the type.
- Recall. Thermosoftening polymers soften and can be remoulded.thermosoftening
- Write the answer. thermosoftening
Check. Poly(ethene) is an example. ✓
Method. Recall the type.
- Recall. Thermosetting polymers do not soften when heated.thermosetting
- Write the answer. thermosetting
Check. Bakelite is a thermosetting plastic. ✓
Method. Recall the structure.
- Recall. Thermosetting polymers have cross-links between chains.cross-links
- Write the answer. cross-links
Check. Cross-links are strong bonds. ✓
Method. Recall the example.
- Recall. Poly(ethene) has separate chains and softens when heated.thermosoftening
- Write the answer. thermosoftening
Check. Poly(ethene) is used for bags. ✓
Method. Recall the examples.
- Recall. Polyester and nylon are condensation polymers.polyester
- Write the answer. Accept polyester or nylon.
Check. Both are made by joining monomers with a small molecule lost. ✓
Method. Recall the byproduct.
- Recall. The small molecule lost is usually water.water
- Write the answer. water
Check. Addition polymers lose nothing. ✓
Method. Think about the property.
- Property. Thermosetting plastics do not soften when hot.do not soften
- Conclude. So the plug keeps its shape and insulates safely.safe
- Write the answer. Accept any sentence that says it does not melt or soften, so it is safe to handle near heat.
Check. The structure is cross-linked. ✓
Method. Think about the heating.
- Heat. The polymer softens when heated.softens
- Conclude. So it can be melted and remoulded into new products.remoulded
- Write the answer. Accept any sentence that says it softens when heated, so it can be remoulded.
Check. Thermosetting polymers cannot be recycled this way. ✓
Biodegradable polymers and the environment
A biodegradable polymer is broken down by microorganisms into simple substances. Many polymers, such as poly(ethene), are non-biodegradable: they remain in landfill for many years. Plastics that are not recycled can litter the land and the sea, and burning them can release toxic gases. Choosing a material means balancing its properties, cost and environmental impact.
Key ideas
- Biodegradable: broken down by microorganisms into simple substances.
- Non-biodegradable: remains for many years; poly(ethene) and PVC are examples.
- Recycling and reuse reduce the waste of polymers.
- Choose a material by its properties, cost and environmental impact.
Method. Recall the property.
- Recall. Poly(ethene) is non-biodegradable, so it stays in landfill for many years.non-biodegradable
- Decide. So the answer is non-biodegradable.non-biodegradable
- Write the answer. non-biodegradable
Check. It is often recycled. ✓
Method. Recall a biodegradable polymer.
- Recall. Starch-based plastics are biodegradable.starch-based
- Decide. Microorganisms break them down into simple substances.breaks down
- Write the answer. Accept any one of: starch-based plastics, PLA.
Check. Microorganisms break these polymers down. ✓
Method. Think about where the plastic goes.
- Look. Plastic that is not recycled often ends up in landfill or litter.landfill or litter
- Conclude. It can stay for many years and harm wildlife.harm wildlife
- Write the answer. it stays for many years and can harm wildlife
Check. Accept any sensible environmental problem. ✓
Watch out
Watch out: “biodegradable” does not mean the material is always better. It depends on the conditions: many biodegradable plastics need a warm, moist composting site to break down.
Exam tip
Exam tip. In an evaluation, give a property, a cost, and an environmental impact for each material, and reach a balanced conclusion.
Exercise 16E Biodegradable polymers and the environment
Method. Recall the definition.
- Recall. Biodegradable materials are broken down by microorganisms.microorganisms
- Write the answer. broken down by microorganisms
Check. Microorganisms are bacteria and fungi. ✓
Method. Recall the property.
- Recall. Poly(ethene) is non-biodegradable.no
- Write the answer. no
Check. It stays in landfill for many years. ✓
Method. Recall the property.
- Recall. PVC is non-biodegradable.no
- Write the answer. no
Check. PVC is used for pipes. ✓
Method. Recall the material.
- Recall. Starch-based plastics are made from plant starch.starch
- Write the answer. Accept starch-based plastics.
Check. Starch comes from crops. ✓
Method. Recall the benefit.
- Recall. Recycling reduces the amount of waste and saves raw materials.reduces waste
- Write the answer. Accept reduces waste or saves raw materials.
Check. Recycling uses less crude oil. ✓
Method. Think about the products.
- Products. Burning plastic can release toxic gases.toxic gases
- Conclude. These gases harm people and the environment.harm
- Write the answer. Accept any sentence that says burning can release toxic gases into the air.
Check. Careful disposal reduces this harm. ✓
Method. Compare the benefits and the drawbacks.
- Benefit. A biodegradable bag breaks down, so it reduces long-term waste.breaks down
- Drawback. It may need composting conditions and can cost more.cost more
- Write the answer. Accept any answer that says the biodegradable bag breaks down, but it may need composting conditions and cost more.
Check. A balanced evaluation gives both sides. ✓
Method. Think about the whole life.
- Properties. The material may be strong and cheap.strong and cheap
- Conclude. But if it is non-biodegradable and not recycled, it harms the environment.harms environment
- Write the answer. Accept any sentence that says its environmental impact, such as non-biodegradable waste, must also be considered.
Check. Choosing materials balances properties and impact. ✓
Chapter summary
| Skill | Method |
|---|---|
| Alcohols | CnH2n+1OH; -OH group; ethanol from fermentation or hydration. |
| Carboxylic acids | -COOH; react with carbonates, alkalis and metals; salts are ethanoates. |
| [H] Esters | Alcohol + carboxylic acid -> ester + water (acid catalyst). |
| Addition polymers | Monomers with C=C join with no other product; repeat unit in brackets. |
| Polymer types | Thermosoftening: separate chains, soften. Thermosetting: cross-linked, do not soften. |
| [H] Condensation polymers | Monomers join with a small molecule (often water) lost each time. |
| Biodegradability | Biodegradable polymers are broken down by microorganisms; poly(ethene) and PVC are not. |
Can you…?
- I can describe the alcohols and the two methods of making ethanol
- I can describe carboxylic acids and their reactions with carbonates, alkalis and metals
- [H] I can describe esters and their formation
- I can draw the repeat unit of an addition polymer from its monomer
- I can compare thermosoftening and thermosetting polymers, and biodegradable and non-biodegradable materials
Key terms
- alcohol
- an organic compound with the -OH functional group
- carboxylic acid
- an organic acid with the -COOH functional group
- fermentation
- the conversion of sugar into ethanol and carbon dioxide by yeast, without air
- monomer
- a small molecule that joins with others to form a polymer
- repeat unit
- the unit of a polymer chain that is repeated; written in brackets
- thermosoftening polymer
- a polymer with separate chains that softens when heated
- thermosetting polymer
- a polymer with cross-linked chains that does not soften when heated
- ester
- [H] a compound formed from an alcohol and a carboxylic acid, with a fruity smell
Exercise 16Z Check-up
Method. Recall the formula.
- Recall. Alcohols are CnH2n+1OH.CnH2n+1OH
- Write the answer. CnH2n+1OH
Check. Ethanol is C2H5OH. ✓
Method. Recall the group.
- Recall. Carboxylic acids have the -COOH group.-COOH
- Write the answer. -COOH
Check. Ethanoic acid is CH3COOH. ✓
Method. Recall the gas.
- Recall. Carbonates release carbon dioxide.carbon dioxide
- Write the answer. carbon dioxide
Check. Chapter 10. ✓
Method. Recall the monomer.
- Recall. Poly(propene) is made from propene.propene
- Write the answer. propene
Check. Propene is C3H6. ✓
Method. Recall the repeat unit.
- Recall. The repeat unit is -CH2-CH2-.-CH2-CH2-
- Write the answer. -CH2-CH2-
Check. Two carbons. ✓
Method. Recall the type.
- Recall. Thermosetting polymers do not soften when heated.thermosetting
- Write the answer. thermosetting
Check. They have cross-links. ✓
Method. Recall the product.
- Recall. Ethene and steam give ethanol.ethanol
- Write the answer. ethanol
Check. The catalyst is phosphoric acid. ✓
Method. Recall the process.
- Recall. Yeast converts sugar to ethanol by fermentation.fermentation
- Write the answer. fermentation
Check. It is anaerobic. ✓
Method. Name the alcohol part and the acid part.
- Ester. Ethyl from ethanol, ethanoate from ethanoic acid.ethyl ethanoate
- Write the answer. ethyl ethanoate
Check. Esters have fruity smells. ✓
Method. Think about the process.
- Yeast. Fermentation uses living yeast.living
- Conclude. So the reaction is slow and depends on the yeast’s conditions.slow
- Write the answer. Accept any sentence that says yeast is a living organism, so the reaction depends on its growth and conditions.
Check. Hydration is a fast chemical reaction with a catalyst. ✓
Total 25 marks. Allow about 25 minutes.
Exercise 16X Exam-style questions
Method. Recall both methods.
- Fermentation. Fermentation uses sugar.sugar
- Hydration. Hydration uses ethene and steam.ethene and steam
- Both. Both give ethanol.ethanol
- Write the answer. fermentation (sugar); hydration (ethene and steam)
Check. Each method has a different feedstock. ✓
Method. Carbonates make a salt, water and carbon dioxide.
- Salt. Magnesium ethanoate.magnesium ethanoate
- Others. Water and carbon dioxide.water and carbon dioxide
- Write the answer. magnesium ethanoate, water and carbon dioxide
Check. The pattern is the same as in Chapter 10. ✓
Method. Recall the repeat unit.
- Recall. PVC is made from chloroethene, CH2=CHCl.chloroethene
- Unit. The repeat unit is -CH2-CHCl-.-CH2-CHCl-
- Write the answer. -CH2-CHCl-
Check. Chlorine is kept in each unit. ✓
Method. Compare the structure and the property.
- Thermosoftening. Separate chains; they soften and can be remoulded.soften
- Thermosetting. Cross-linked chains; they do not soften when heated.cross-linked
- Write the answer. Accept any answer that says thermosoftening polymers have separate chains and soften, while thermosetting polymers have cross-links and do not soften.
Check. Both properties are needed for full marks. ✓
Method. Think about the source.
- Source. The sugar is from plants.plants
- Conclude. Crops can be grown again, so the source is renewable.renewable
- Write the answer. Accept any sentence that says the sugar comes from crops, which can be grown again.
Check. Crude oil is a finite resource. ✓
Method. Recall the ester and the other product.
- Ester. The ester is ethyl ethanoate.ethyl ethanoate
- Other. Water is the other product.water
- Write the answer. ethyl ethanoate
Check. Ethyl ethanoate has a fruity smell. ✓
Method. Keep the methyl group on the middle carbon.
- Monomer. Propene is CH2=CHCH3.propene
- Unit. The repeat unit is -CH(CH3)-CH2-.-CH(CH3)-CH2-
- Write the answer. -CH(CH3)-CH2-
Check. Methyl on each unit. ✓
Method. Think about its properties.
- Property. Poly(ethene) is non-biodegradable.non-biodegradable
- Effect. It stays in landfill or litter for many years, harming wildlife.many years
- Write the answer. Accept any answer that says it is non-biodegradable and stays in landfill or litter for many years.
Check. Recycling reduces the problem. ✓
Method. Think about the reaction.
- Lost. A small molecule, such as water, is lost.lost
- Conclude. This happens each time two monomers join.each time
- Write the answer. Accept any sentence that says a small molecule, such as water, is lost each time two monomers join.
Check. Addition polymers lose no atoms. ✓
Method. Recall both groups.
- Alcohol. The functional group of an alcohol is -OH.-OH
- Acid. The functional group of a carboxylic acid is -COOH.-COOH
- Write the answer. -OH, -COOH
Check. Both are important in organic chemistry. ✓