The periodic table and bonding
By the end of this chapter you will be able to
- Describe Mendeleev’s periodic table, and how groups and periods show patterns
- Draw electron arrangements for the first 20 elements and link them to the group
- Explain ionic bonding by transfer, with ion charges and formulae
- Explain covalent bonding by sharing, with simple molecules and their formulae
- Explain how giant structures and metallic bonding account for melting point and conduction
You should already know
- Atoms, elements and the periodic table (Year 8 Science, Chapter 7)
- Chemical symbols and formulae (Year 7 and Year 8 Science)
Where this leads
- Reactivity and the reactivity series in Chapter 7, which uses the metals in this table
National Curriculum for England, Key Stage 3 science, Year 9. Content: 9C1 development of the periodic table: Mendeleev, gaps and ordering; groups and periods; electron arrangement of the first 20 elements, 9C1 metals and non-metals; noble gases; transition metals; patterns in properties (deepens Year 8, Chapter 7), 9C2 ionic bonding by transfer of electrons (ions and charges); covalent bonding by sharing (simple molecules and formulae), 9C2 giant structures (sodium chloride lattice, diamond, graphite) and metallic bonding (basic), and how bonding explains melting point and electrical conductivity.
Exercise P Do you remember?
Method. Recall the symbol.
- Recall. The symbol for sodium comes from its Latin name, natrium.natrium
- Write the answer. Na
Check. Na is the symbol for sodium. ✓
Method. Recall the particle.
- Recall. The neutron has no charge and sits in the nucleus.no charge
- Write the answer. neutron
Check. Protons are positive; electrons are negative. ✓
Method. Multiply 4 by 6.
- Multiply. Four lots of 6 is 24.4 x 6 = 24
- Write the answer. 24
Check. 24 divided by 4 is 6. ✓
Method. Recall the word.
- Recall. A substance with only one type of atom is an element.one type of atom
- Write the answer. element
Check. Compounds have two or more elements. ✓
Method. Use the atomic number.
- Look up. The atomic number of oxygen is 8.atomic number 8
- Conclude. So an oxygen atom has 8 protons.8 protons
- Write the answer. 8
Check. The atomic number is the number of protons. ✓
Mendeleev and the periodic table
Mendeleev arranged the elements in order of their atomic mass, and placed elements with similar properties in the same group. The vertical columns are groups, and the horizontal rows are periods. Elements in the same group react in similar ways.
Most elements are metals, found on the left and in the middle. Non-metals are on the right. The noble gases form group 0, and the metals in the middle are the transition metals.
Key ideas
- Mendeleev ordered the elements and left gaps for undiscovered ones.
- Groups are vertical columns with similar properties; periods are rows.
- Metals are on the left and middle; non-metals are on the right.
- Group 0 holds the noble gases, which are unreactive.
Method. Think about what a gap means.
- Think. A gap is a place for an element that had not been found yet.not been found
- Name it. So the gaps showed undiscovered elements.undiscovered elements
- Write the answer. undiscovered elements
Check. Some predictions were later confirmed. ✓
Method. Recall the group of noble gases.
- Recall. The noble gases are unreactive and form group 0.group 0
- Name it. So the noble gases are in group 0.0
- Write the answer. 0
Check. Helium, neon and argon are noble gases. ✓
Method. Find the element in the first column.
- Look. Group 1 contains lithium, sodium and potassium.lithium, sodium, potassium
- Name it. The second element in group 1 is sodium.sodium
- Write the answer. sodium
Check. Lithium is first and potassium is third. ✓
Watch out
Watch out: Mendeleev ordered by atomic mass, and the modern table orders by atomic number. The idea of groups and periods is the same.
Exam tip
Exam tip. A period is a row across the table; a group is a column down the table.
Try it (with your teacher, or a grown-up at home). With your teacher, look at a copy of the periodic table. Circle the elements in group 1, then group 0. Write down one property of each group that you can see from the table. Do not heat or mix any of the chemicals.
Exercise 6A Mendeleev and the periodic table
Method. Recall the name.
- Recall. Vertical columns are groups.groups
- Write the answer. groups
Check. Rows are periods. ✓
Method. Recall the name.
- Recall. Horizontal rows are periods.periods
- Write the answer. periods
Check. Elements in one group have similar properties. ✓
Method. Recall where non-metals are.
- Recall. Non-metals are on the right of the table.on the right
- Write the answer. non-metals
Check. Most elements are metals. ✓
Method. Recall the group.
- Recall. The noble gases form group 0.group 0
- Write the answer. 0
Check. Noble gases are very unreactive. ✓
Method. Recall the property.
- Recall. The noble gases have full outer shells, so they do not react easily.do not react easily
- Write the answer. unreactive
Check. Helium, neon and argon are unreactive. ✓
Method. Read the top of group 1.
- Read. The first element in group 1 is lithium.lithium
- Write the answer. lithium
Check. Lithium, sodium and potassium are group 1. ✓
Method. Find the halogens.
- Find. Fluorine and chlorine are the group 7 elements in the first 20.fluorine and chlorine
- Write. Their symbols are F and Cl.F and Cl
- Write the answer. F and Cl
Check. Group 7 elements have seven outer electrons. ✓
Method. Count the rows of the table shown.
- Count. The rows are periods 1, 2, 3 and 4.periods 1 to 4
- Total. So there are 4 periods.4
- Write the answer. 4
Check. Period 1 has hydrogen and helium. ✓
Method. Count the elements in row 2.
- Count. Period 2 is lithium, beryllium, boron, carbon, nitrogen, oxygen, fluorine and neon.lithium to neon
- Total. That is 8 elements.8
- Write the answer. 8
Check. Period 2 runs from lithium to neon. ✓
Method. Recall the two numbers.
- Recall. The atomic number is the number of protons in an atom.number of protons
- Name it. So the modern table is ordered by atomic number.atomic number
- Write the answer. atomic number
Check. Atomic number is the number of protons. ✓
Method. Think about the outer electrons.
- Think. Elements in one group have the same number of outer electrons.same number of outer electrons
- Conclude. So they react in similar ways.similar ways
- Write the answer. Accept any sentence saying they have the same number of outer electrons.
Check. Outer electrons decide how an element reacts. ✓
Method. Think about keeping the pattern.
- Think. The pattern of properties would break if a place were missing.pattern would break
- Conclude. So he left a gap, and predicted the properties of the missing element.predicted the properties
- Write the answer. Accept any sentence saying the gaps kept elements with similar properties in the same group, so the pattern held.
Check. Predictions were tested by later discoveries. ✓
Electron arrangements of the first 20 elements
Electrons are arranged in shells around the nucleus. The first shell holds up to 2 electrons, and the second and third shells hold up to 8 each in the first 20 elements. The number of electrons in the outer shell is linked to the group: group 1 atoms have 1 outer electron, and group 7 atoms have 7.
Atoms with a full outer shell, such as neon and argon, are very unreactive. Other atoms gain, lose or share electrons to get a full outer shell.
| Symbol | Element | Atomic number | Electrons in each shell |
|---|---|---|---|
| H | hydrogen | 1 | 1 |
| C | carbon | 6 | 2, 4 |
| O | oxygen | 8 | 2, 6 |
| Na | sodium | 11 | 2, 8, 1 |
| Mg | magnesium | 12 | 2, 8, 2 |
| Cl | chlorine | 17 | 2, 8, 7 |
| Ar | argon | 18 | 2, 8, 8 |
| K | potassium | 19 | 2, 8, 8, 1 |
| Ca | calcium | 20 | 2, 8, 8, 2 |
Key ideas
- Shell 1 holds 2 electrons; shells 2 and 3 hold up to 8 each (first 20 elements).
- Total electrons equal the atomic number (the number of protons).
- The outer shell gives the group: group 1 has 1, group 7 has 7.
- A full outer shell makes an atom unreactive.
Method. Fill the shells, 2 then 8, then the rest.
- Fill. Shell 1 holds 2 electrons, shell 2 holds 8.2, 8
- Count. The remaining electrons are 11 - 2 - 8 = 1, in shell 3.11 - 10 = 1
- Write. So the arrangement is 2, 8, 1.2, 8, 1
- Write the answer. 2, 8, 1
Check. The total is 11 electrons. ✓
Method. Count the electrons in the outer shell.
- Count. Chlorine has 2, 8, 7, so 7 electrons in the outer shell.7 outer
- Name it. Seven outer electrons means group 7.group 7
- Write the answer. 7
Check. Group 7 atoms have seven outer electrons. ✓
Method. Look at its outer shell.
- Look. Argon has 2, 8, 8, so its outer shell is full.full outer shell
- Name it. A full outer shell makes it unreactive.unreactive
- Write the answer. full outer shell
Check. Noble gases have full outer shells. ✓
Watch out
Watch out: the number of electrons in an atom equals its atomic number, not its mass number.
Exam tip
Exam tip. Fill shell 1 first (2), then shell 2 (8), then shell 3 (up to 8). Check the total is the atomic number.
Try it (with your teacher, or a grown-up at home). With your teacher, use coloured counters on a paper template with circles for shells. Build sodium (2, 8, 1) and chlorine (2, 8, 7). Say which group each one belongs to, from its outer counters. This is a model, not a real atom.
Exercise 6B Electron arrangements of the first 20 elements
Method. Recall the first shell.
- Recall. The first shell holds up to 2 electrons.up to 2
- Write the answer. 2
Check. Helium has 2 electrons in its first shell. ✓
Method. Recall the second shell.
- Recall. The second shell holds up to 8 electrons.up to 8
- Write the answer. 8
Check. Neon has 2, 8. ✓
Method. Fill the shells.
- Fill. Carbon has 6 electrons: 2 in shell 1, then 4 in shell 2.2 + 4 = 6
- Write. So the arrangement is 2, 4.2, 4
- Write the answer. 2, 4
Check. The total is 6 electrons. ✓
Method. Fill the shells.
- Fill. Oxygen has 8 electrons: 2 in shell 1, then 6 in shell 2.2 + 6 = 8
- Write. So the arrangement is 2, 6.2, 6
- Write the answer. 2, 6
Check. The total is 8 electrons. ✓
Method. Use the arrangement of magnesium.
- Look. Magnesium has 2, 8, 2.2, 8, 2
- Count. The outer shell has 2 electrons.2
- Write the answer. 2
Check. Magnesium is in group 2. ✓
Method. Count the outer electrons of sodium.
- Look. Sodium is 2, 8, 1, with 1 outer electron.1 outer
- Name it. One outer electron means group 1.group 1
- Write the answer. 1
Check. Sodium is an alkali metal. ✓
Method. Count the outer electrons of calcium.
- Look. Calcium is 2, 8, 8, 2, with 2 outer electrons.2 outer
- Name it. Two outer electrons means group 2.group 2
- Write the answer. 2
Check. Calcium and magnesium are in the same group. ✓
Method. Use the atomic number.
- Look. Potassium has atomic number 19.atomic number 19
- Conclude. An atom has as many electrons as its atomic number, so 19.19
- Write the answer. 19
Check. 2 + 8 + 8 + 1 = 19. ✓
Method. Fill the shells, 2 then 8 then 8, then the rest.
- Fill. Shell 1 has 2, shell 2 has 8, shell 3 has 8.2, 8, 8
- Count. The last electron goes in shell 4: 19 - 18 = 1.19 - 18 = 1
- Write. So the arrangement is 2, 8, 8, 1.2, 8, 8, 1
- Write the answer. 2, 8, 8, 1
Check. The sum is 19. ✓
Method. Match the arrangement.
- Look. The arrangement 2, 8, 7 has 17 electrons.17 electrons
- Name it. Atomic number 17 is chlorine.chlorine
- Write the answer. chlorine
Check. Chlorine is in group 7. ✓
Method. Look at the outer shell.
- Look. Neon has 2, 8, so its outer shell has 8 electrons.8 electrons
- Conclude. A full outer shell makes it unreactive.unreactive
- Write the answer. Accept any sentence saying its outer shell is full with 8 electrons.
Check. A full shell does not need to gain or lose electrons. ✓
Method. Compare the outer shells.
- Compare. Sodium is 2, 8, 1 and potassium is 2, 8, 8, 1.1 outer electron each
- Conclude. Both have one outer electron, so they react in similar ways.similar ways
- Write the answer. Accept any sentence saying both have one electron in the outer shell.
Check. The outer shell decides the reactions. ✓
Ionic bonding
In ionic bonding, electrons are transferred from a metal atom to a non-metal atom. The metal atom becomes a positive ion, and the non-metal becomes a negative ion. Opposite charges attract, and this attraction is the ionic bond.
Sodium loses one electron to form Na+. Chlorine gains one electron to form Cl-. The charges balance, so the formula is NaCl.
Key ideas
- Ionic bonding: a metal transfers electrons to a non-metal.
- Metal atoms become positive ions; non-metal atoms become negative ions.
- Opposite charges attract, which is the ionic bond.
- The formula balances the charges: NaCl, MgO, CaCl2.
Method. Think about the electron lost.
- Think. Losing one negative electron leaves one more proton than electrons.one more proton
- Name it. So the ion has a charge of +1.+1
- Write the answer. +1
Check. Sodium forms Na+. ✓
Method. Balance the charges.
- Balance. The charges are +2 and -2, which balance with one of each.+2 and -2
- Write. So the formula is one Mg and one O.MgO
- Write the answer. MgO
Check. The total charge is zero. ✓
Method. Balance the charges.
- Balance. Ca is +2, so it needs two Cl- ions to balance.two Cl ions
- Write. So the formula is one Ca and two Cl.CaCl2
- Write the answer. CaCl2
Check. +2 and two -1 make zero. ✓
Watch out
Watch out: the metal is always the positive ion, and the non-metal the negative ion. Do not write Cl+.
Exam tip
Exam tip. Write the charges first, then choose the numbers of each ion so the total charge is zero.
Try it (with your teacher, or a grown-up at home). With your teacher, look at a model of sodium chloride, or a picture of the lattice. Count the sodium and chloride ions in a small block. Say how many of each you see, and why the ratio is one to one.
Exercise 6C Ionic bonding
Method. Recall what moves.
- Recall. Electrons are transferred from a metal to a non-metal.Electrons are transferred
- Write the answer. electrons
Check. Protons stay in the nucleus. ✓
Method. Recall the rule.
- Recall. Metal atoms lose electrons to become positive ions.lose electrons
- Write the answer. lose
Check. Non-metals gain electrons. ✓
Method. Recall the rule.
- Recall. Non-metal atoms gain electrons, so they become negative ions.gain electrons
- Write the answer. negative
Check. Chloride is Cl-. ✓
Method. Sodium loses one electron.
- Think. Sodium loses one electron.loses one electron
- Name it. So the ion has a charge of +1.+1
- Write the answer. +1
Check. Na+ is the sodium ion. ✓
Method. Magnesium loses two electrons.
- Think. Magnesium is in group 2, so it loses two electrons.two electrons
- Name it. So the ion has a charge of +2.+2
- Write the answer. +2
Check. Mg2+ is the magnesium ion. ✓
Method. Recall the bond.
- Recall. Opposite charges attract, which is the ionic bond.opposite charges attract
- Write the answer. ionic bond
Check. Ionic bonds hold the lattice together. ✓
Method. Balance the charges.
- Balance. Na+ and Cl- have charges of +1 and -1.+1 and -1
- Write. One of each gives NaCl.NaCl
- Write the answer. NaCl
Check. The total charge is zero. ✓
Method. Balance the charges.
- Balance. Mg2+ and O2- have charges of +2 and -2.+2 and -2
- Write. One of each gives MgO.MgO
- Write the answer. MgO
Check. The total charge is zero. ✓
Method. Balance the charges.
- Balance. Ca2+ needs two Cl- ions to balance the charge.two Cl- ions
- Write. So the formula is CaCl2.CaCl2
- Write the answer. CaCl2
Check. +2 and -2 make zero. ✓
Method. Compare the charges.
- Compare. Na+ has +1 and Cl- has -1.+1 and -1
- Count. One chloride ion balances one sodium ion.1
- Write the answer. 1
Check. The ratio is one to one. ✓
Method. Think about the attraction.
- Think. The ions are held by strong attractions.strong attractions
- Conclude. A lot of energy is needed to break them, so the melting point is high.high melting point
- Write the answer. Accept any sentence saying strong attractions between ions in the lattice need a lot of energy to break.
Check. Strong bonds need more heat to melt. ✓
Method. Think about moving charges.
- Think. Electricity needs charged particles that can move.charged particles that can move
- Conclude. In the solid the ions are fixed; when molten they are free to move.free to move
- Write the answer. Accept any sentence saying the ions are fixed in the solid, but free to move when molten.
Check. Charged particles must be free to carry charge. ✓
Covalent bonding and simple molecules
In covalent bonding, atoms share pairs of electrons. Each shared pair is one covalent bond. The atoms in a simple molecule are held together by covalent bonds, and the molecules are held apart by much weaker forces.
Hydrogen (H2) has one shared pair. Water (H2O) has two covalent bonds. Methane (CH4) has four. Carbon dioxide (CO2) has four shared pairs, in two double bonds.
| Molecule | Formula | Bonds |
|---|---|---|
| hydrogen, H2 | H2 | 1 |
| water, H2O | H2O | 2 |
| methane, CH4 | CH4 | 4 |
| carbon dioxide, CO2 | CO2 | 4 |
Key ideas
- Covalent bonding: atoms share pairs of electrons.
- Simple molecules have weak forces between molecules, so low melting points.
- Simple molecules do not conduct electricity, as they have no free charges.
- The formula shows the atoms in a molecule, for example H2O.
Method. Count the shared pairs.
- Count. The oxygen shares one pair with each hydrogen.one pair with each
- Total. So there are 2 shared pairs, which is 2 bonds.2
- Write the answer. 2
Check. Two hydrogens, two bonds. ✓
Method. Count the atoms of each element.
- Count. One carbon and four hydrogen atoms.one C and four H
- Write. So the formula is CH4.CH4
- Write the answer. CH4
Check. Methane has four bonds. ✓
Method. Think about what breaks on melting.
- Think. Melting breaks the weak forces between molecules, not the covalent bonds.weak forces between molecules
- Conclude. Weak forces need little energy, so the melting point is low.little energy
- Write the answer. weak forces between molecules
Check. The covalent bonds inside the molecules stay intact. ✓
Watch out
Watch out: melting a simple molecular substance breaks the weak forces between molecules, not the covalent bonds inside them.
Exam tip
Exam tip. Write the formula by counting each atom, not each bond. Subscripts show how many of each atom.
Try it (with your teacher, or a grown-up at home). With your teacher, use drawing and modelling kits or paper: draw dots for the electrons in a hydrogen molecule (H2) and water (H2O). Show each shared pair with a line, and count the bonds.
Exercise 6D Covalent bonding and simple molecules
Method. Recall what is shared.
- Recall. Atoms share pairs of electrons in covalent bonding.share pairs of electrons
- Write the answer. electrons
Check. Metals and non-metals are not both sharing in the same way. ✓
Method. Count the shared pairs.
- Count. The two hydrogen atoms share one pair of electrons.one pair
- Write the answer. 1
Check. One shared pair is one bond. ✓
Method. Count the shared pairs.
- Count. Oxygen shares a pair with each of two hydrogens.two hydrogens
- Total. So there are 2 bonds.2
- Write the answer. 2
Check. H2O has two O-H bonds. ✓
Method. Count the atoms.
- Count. One carbon and four hydrogens.1 C and 4 H
- Write. So the formula is CH4.CH4
- Write the answer. CH4
Check. Four hydrogen atoms bond to one carbon. ✓
Method. Count the atoms.
- Count. One carbon and two oxygen atoms.1 C and 2 O
- Write. So the formula is CO2.CO2
- Write the answer. CO2
Check. Carbon dioxide has two double bonds. ✓
Method. Think about charged particles.
- Think. Simple molecules have no free charged particles.no free charged
- Decide. So they do not conduct electricity; the answer is no.no
- Write the answer. no
Check. Covalent molecules have no overall charge. ✓
Method. Recall the forces.
- Recall. Only the weak forces between molecules are broken on melting.weak forces
- Write the answer. low
Check. Weak forces need little energy. ✓
Method. Read the formula H2O.
- Read. The subscript 2 after H shows two hydrogen atoms.subscript 2
- Write the answer. 2
Check. O has no subscript, so it is one oxygen atom. ✓
Method. Add the atoms in the formula.
- Add. One carbon and two oxygen atoms.1 + 2
- Total. So there are 3 atoms.1 + 2 = 3
- Write the answer. 3
Check. One C, two O. ✓
Method. Count the bonds from the carbon.
- Count. Carbon forms four covalent bonds, one to each hydrogen.four bonds
- Total. So methane has 4 shared pairs.4
- Write the answer. 4
Check. Four hydrogens, four bonds. ✓
Method. Think about what melting breaks.
- Think. Melting breaks the forces between molecules.forces between molecules
- Conclude. The strong covalent bonds inside the molecule stay intact.stay intact
- Write the answer. Accept any sentence saying melting breaks the weak forces between molecules, not the strong covalent bonds.
Check. Two different kinds of force are involved. ✓
Method. Think about what carries charge.
- Think. Electricity needs charged particles that can move.charged particles
- Conclude. Oxygen molecules have no free charged particles, so no current flows.no current
- Write the answer. Accept any sentence saying it has no free charged particles that can carry the current.
Check. Covalent bonds hold electrons in place. ✓
Giant structures and metallic bonding
A giant covalent structure has millions of atoms joined by covalent bonds. In diamond, each carbon bonds to four others in a rigid lattice, so it is very hard with a very high melting point. In graphite, each carbon bonds to three others in flat layers. Each carbon has one electron that is free to move, so graphite conducts electricity.
In metallic bonding, metal atoms lose their outer electrons, which move freely through the metal. The positive metal ions are held together by these shared electrons. This explains why metals conduct electricity and can be bent without breaking.
| Substance | Type of bonding | Melting point and state | Electrical conduction |
|---|---|---|---|
| sodium chloride | ionic | high, solid | conducts when molten or dissolved |
| water | covalent (simple molecule) | low, liquid | does not conduct |
| diamond | giant covalent | very high, solid | does not conduct |
| copper | metallic | high, solid | conducts when solid |
Key ideas
- Diamond: each carbon bonds to four others; very hard, very high melting point, does not conduct.
- Graphite: layers of carbon; each carbon has one free electron, so it conducts.
- Metals: positive ions in a sea of free electrons; they conduct and can be bent.
- Ionic compounds conduct only when molten or dissolved, when the ions can move.
Method. Recall the structure.
- Recall. Each carbon in diamond is covalently bonded to four others.four others
- Name it. So the number is 4.4
- Write the answer. 4
Check. Four bonds make a rigid lattice. ✓
Method. Recall the free electrons.
- Recall. Each carbon in graphite has one free electron, which can carry a current.free electron
- Decide. So graphite conducts electricity, and the answer is yes.yes
- Write the answer. yes
Check. Diamond does not, because all its electrons are fixed in bonds. ✓
Method. Recall the name.
- Recall. The outer electrons in a metal move freely through the metal.move freely
- Name it. These are called delocalised electrons.delocalised electrons
- Write the answer. delocalised electrons
Check. They carry electricity through the metal. ✓
Watch out
Watch out: diamond and graphite are both pure carbon, but their structures differ, so their properties differ.
Exam tip
Exam tip. Explain conduction with the word free or delocalised electrons, and explain a high melting point with strong bonds that need much energy to break.
Try it (with your teacher, or a grown-up at home). With your teacher, test a pencil lead (graphite) and a metal paper clip in a simple circuit with a low-voltage cell and a bulb. Do not use mains electricity. Say which one lets the current through, and why.
Exercise 6E Giant structures and metallic bonding
Method. Recall the structure.
- Recall. Millions of atoms joined by covalent bonds form a giant covalent structure.millions of atoms
- Write the answer. giant covalent structure
Check. Diamond is one example. ✓
Method. Recall the structure.
- Recall. Each carbon in diamond bonds to four others.four others
- Write the answer. 4
Check. Four bonds around each carbon. ✓
Method. Recall the structure.
- Recall. In graphite, each carbon bonds to three others in a layer.three others
- Write the answer. 3
Check. Layers of hexagons each have three bonds. ✓
Method. Recall the property.
- Recall. Diamond has a rigid lattice of strong bonds, so it is very hard.rigid lattice
- Write the answer. hard
Check. Its strong bonds make it hard. ✓
Method. Recall the free electrons.
- Recall. Metals have free electrons that carry a current.free electrons
- Write the answer. yes
Check. Metals conduct because electrons move through them. ✓
Method. Recall the name.
- Recall. The outer electrons move freely as delocalised electrons.move freely
- Write the answer. delocalised electrons
Check. They form a sea around the ions. ✓
Method. Recall the free electrons.
- Recall. Each carbon in graphite has one free electron.one free electron
- Decide. So graphite conducts, and the answer is yes.yes
- Write the answer. yes
Check. Diamond has no free electrons. ✓
Method. Recall the bonding in diamond.
- Recall. All of the outer electrons of carbon in diamond are fixed in bonds.fixed in bonds
- Decide. So diamond does not conduct, and the answer is no.no
- Write the answer. no
Check. Diamond and graphite are both carbon, with different bonding. ✓
Method. Compare the bonds to be broken.
- Compare. Melting diamond breaks strong covalent bonds, but melting water breaks only weak forces.strong covalent bonds
- Decide. So diamond has the higher melting point.diamond
- Write the answer. diamond
Check. Giant structures need more energy to melt. ✓
Method. Think about the layers.
- Think. The metal ions are arranged in layers.arranged in layers
- Conclude. The layers can slide, and the shared electrons still hold them together.still hold them
- Write the answer. Accept any sentence saying the layers of positive ions can slide over each other while the electrons keep them held together.
Check. Metallic bonding is not directional like covalent bonding. ✓
Method. Compare the structures.
- Compare. Graphite has weak forces between its layers, so they slide.layers slide
- Conclude. Diamond’s rigid lattice of strong bonds does not slide.does not slide
- Write the answer. Accept any sentence saying graphite’s layers slide over each other, while diamond’s rigid lattice of bonds does not.
Check. Structure decides the property. ✓
Chapter summary
| Skill | Method |
|---|---|
| Periodic table | Mendeleev ordered by atomic mass and left gaps; groups share properties; periods are rows; noble gases are group 0. |
| Electron arrangement | Shell 1 holds 2; shells 2 and 3 hold up to 8; outer electrons give the group. |
| Ionic bonding | Electrons are transferred from a metal to a non-metal, forming ions with opposite charges; formulae balance the charges. |
| Covalent bonding | Atoms share pairs of electrons; simple molecules have low melting points and do not conduct. |
| Giant structures | Diamond: four bonds per carbon, very hard; graphite: layers, one free electron per carbon, conducts. |
| Metallic bonding | Positive ions in a sea of delocalised electrons; metals conduct and can be bent. |
Can you…?
- I can describe Mendeleev’s table, groups and periods, and metals and non-metals
- I can draw electron arrangements for the first 20 elements and link them to a group
- I can explain ionic bonding by transfer, and write the formula of an ionic compound
- I can explain covalent bonding, and write the formula of a simple molecule
- I can explain melting point and conduction using giant structures and metallic bonding
Key terms
- group
- a vertical column in the periodic table, with elements of similar properties
- period
- a horizontal row in the periodic table
- noble gas
- an unreactive element in group 0, with a full outer shell
- transition metal
- a metal in the middle block of the periodic table
- shell
- a layer of electrons around the nucleus of an atom
- ion
- an atom or group of atoms with an electrical charge
- ionic bond
- the attraction between oppositely charged ions
- covalent bond
- the bond formed when atoms share a pair of electrons
- molecule
- a group of atoms held together by covalent bonds
- giant structure
- a structure with millions of atoms held together by bonds
- lattice
- a regular arrangement of particles in a solid
- delocalised electron
- an electron in a metal that is free to move through it
Exercise 6Z Check-up
Method. Recall the name.
- Recall. Vertical columns are groups.groups
- Write the answer. groups
Check. Rows are periods. ✓
Method. Fill the shells.
- Fill. Shell 1 has 2, shell 2 has 8, and 1 is left in shell 3.2, 8, 1
- Write the answer. 2, 8, 1
Check. The total is 11. ✓
Method. Count the outer electrons.
- Count. Chlorine has 7 outer electrons.7 outer
- Name it. So chlorine is in group 7.group 7
- Write the answer. 7
Check. Group 7 atoms have seven outer electrons. ✓
Method. Sodium loses one electron.
- Think. Sodium loses one electron, so the ion is +1.+1
- Write the answer. +1
Check. Na+ is the sodium ion. ✓
Method. Balance the charges.
- Balance. Mg2+ and O2- balance with one of each.one of each
- Write the answer. MgO
Check. +2 and -2 make zero. ✓
Method. Count the atoms.
- Count. One carbon and two oxygen atoms.1 C and 2 O
- Write the answer. CO2
Check. Carbon dioxide has two double bonds. ✓
Method. Count the hydrogens.
- Count. Carbon bonds to four hydrogen atoms.four hydrogens
- Write the answer. 4
Check. One bond to each hydrogen. ✓
Method. Recall the free electrons.
- Recall. The free electrons in a metal are delocalised.delocalised
- Write the answer. yes
Check. They move through the metal. ✓
Method. Recall the bonding.
- Recall. All of diamond’s outer electrons are fixed in bonds.fixed in bonds
- Write the answer. no
Check. Graphite conducts, diamond does not. ✓
Method. Think about the forces.
- Think. Only weak forces between molecules are broken on melting.weak forces
- Conclude. That needs little energy, so the melting point is low.little energy
- Write the answer. Accept any sentence saying the weak forces between molecules are broken on melting, which needs little energy.
Check. The covalent bonds stay intact. ✓
Total 18 marks. Allow about 18 minutes.
Exercise 6X Practice test questions
Method. Recall the group.
- Recall. The noble gases form group 0.group 0
- Write the answer. 0
Check. Noble gases are unreactive. ✓
Method. Fill the shells.
- Fill. Shell 1 has 2, shell 2 has 8, shell 3 has 7.2, 8, 7
- Write the answer. 2, 8, 7
Check. The total is 17. ✓
Method. Balance the charges.
- Balance. Na+ and Cl- balance with one of each.one of each
- Write the answer. NaCl
Check. The charges sum to zero. ✓
Method. Recall the bonding.
- Recall. Sharing pairs of electrons is covalent bonding.sharing pairs
- Write the answer. covalent bonding
Check. Ionic bonding transfers electrons. ✓
Method. Balance the charges.
- Balance. Ca2+ needs two Cl- ions to balance.two Cl- ions
- Write. So the formula is CaCl2.CaCl2
- Write the answer. CaCl2
Check. +2 and two -1 make zero. ✓
Method. Think about moving charges.
- Think. Electricity needs charged particles that can move.can move
- Conclude. The ions are fixed in the solid, but free to move when molten.free to move
- Write the answer. Accept any sentence saying the ions are free to move when molten, but are fixed in the solid.
Check. Charged particles must be free to move. ✓
Method. Think about the table.
- Think. Periods run across the table, and groups run down it.across and down
- Conclude. So a period is a row, and a group is a column.row
- Write the answer. Accept any sentence saying a period is a row and a group is a column.
Check. Groups share similar properties. ✓
Method. Think about the bonds.
- Think. Each carbon is joined to four others by strong bonds.four others
- Conclude. Breaking them needs a lot of energy, so the melting point is high.a lot of energy
- Write the answer. Accept any sentence saying each carbon is joined to four others by strong covalent bonds, which need much energy to break.
Check. Giant structures need more energy to melt. ✓
Method. Count the shared pairs, then explain.
- Count. Oxygen shares one pair with each hydrogen, so 2 shared pairs.2 shared pairs
- Explain. Oxygen has 6 outer electrons and needs 2 more to fill its shell.needs 2 more
- Conclude. So the oxygen forms two bonds.two bonds
- Write the answer. Accept any answer giving 2, with oxygen needing two more electrons to complete its outer shell.
Check. Each hydrogen shares one pair. ✓
Method. Think about the electrons in the metal.
- Think. The outer electrons are delocalised and can move freely.delocalised
- Conclude. When a voltage is applied, they carry a current through the metal.carry a current
- Write the answer. Accept any answer saying the outer electrons are delocalised and move freely, carrying a current through the metal.
Check. Free electrons are the charge carriers. ✓