Electron arrangement and the periodic table
By the end of this chapter you will be able to
- Write the electron arrangement of an element from its atomic number
- Use the periodic table to find the group and period of an element
- Use the number of outer electrons to find the group number
- Explain how Mendeleev arranged the elements, and why the modern table is ordered by atomic number
- Compare metals and non-metals, and describe transition metals and noble gases
You should already know
- Atomic number and the protons in an atom (Chapter 1)
- The atom and its shells (Chapter 1)
Where this leads
- Reactivity of metals and halogens (Chapter 3)
- Ionic bonding from outer electrons (Chapter 4)
- Covalent bonding and noble gas stability (Chapter 5)
GCSE Chemistry. Content follows the GCSE (9-1) subject content for England (Edexcel and AQA). Content references: Describe electron shells and write electronic configurations for the first 20 elements, Explain that the periodic table is ordered by atomic number, with groups and periods, Predict properties of an element from its group, including the noble gases, Describe how the periodic table was developed, including Mendeleev’s gaps, Distinguish metals from non-metals, describe transition metals and explain the stability of noble gases.
Exercise P Do you remember?
Method. The atomic number is the number of protons.
- Read. Sodium has atomic number 11, so it has 11 protons.atomic number 11
- Write the answer. 11
Check. In a neutral atom the number of electrons is also 11. ✓
Method. Multiply before you add.
- Multiply. 2 x 3 = 6.2 x 3 = 6
- Add. Then add 2: 2 + 6 = 8.2 + 6 = 8
- Write the answer. 8
Check. Doing the addition first would give 12, which is wrong. ✓
Method. Multiply 2 by itself three times.
- Multiply. 2 x 2 x 2 = 8.2 x 2 x 2 = 8
- Write the answer. 8
Check. 2 squared is 4, and 4 x 2 = 8. ✓
Method. Share 36 into 6 equal groups.
- Divide. Each group has 36 / 6 = 6.36 / 6 = 6
- Write the answer. 6
Check. 6 x 6 = 36. ✓
Method. Negative numbers are smaller than positive numbers.
- Compare. Five is positive and minus three is negative, so 5 is larger.5 > -3
- Write the answer. 5
Check. On a number line, 5 is to the right of -3. ✓
Electron shells and electronic configuration
Electrons move in shells around the nucleus. For the first 20 elements, the first shell holds up to 2 electrons, and the second and third shells each hold up to 8 electrons. The electronic configuration lists the number of electrons in each shell, for example 2,8,1 for sodium.
| Atomic number | Element | Electron arrangement | Total electrons | Shells |
|---|---|---|---|---|
| 1 | hydrogen (H) | 1 | 1 | 1 |
| 2 | helium (He) | 2 | 2 | 1 |
| 6 | carbon (C) | 2,4 | 6 | 2 |
| 10 | neon (Ne) | 2,8 | 10 | 2 |
| 11 | sodium (Na) | 2,8,1 | 11 | 3 |
| 12 | magnesium (Mg) | 2,8,2 | 12 | 3 |
| 17 | chlorine (Cl) | 2,8,7 | 17 | 3 |
| 18 | argon (Ar) | 2,8,8 | 18 | 3 |
| 19 | potassium (K) | 2,8,8,1 | 19 | 4 |
| 20 | calcium (Ca) | 2,8,8,2 | 20 | 4 |
Key ideas
- The first shell holds up to 2 electrons; the second and third hold up to 8 each.
- The total of the numbers in the arrangement equals the atomic number.
- The number of shells equals the period number.
- The outer shell is the shell with the highest number.
Method. Use the atomic number and fill the shells in order.
- Atomic number. Oxygen has 8 electrons.8 electrons
- Fill the first shell. The first shell takes 2.2 in shell 1
- Fill the second shell. The rest, 8 - 2 = 6, go in the second shell.6 in shell 2
- Write the answer. 2,6
Check. 2 + 6 = 8, the atomic number of oxygen. ✓
Method. Fill the shells in order and check the total.
- Atomic number. Magnesium has 12 electrons.12 electrons
- First two shells. Shell 1 takes 2 and shell 2 takes 8, a total of 10.2 + 8 = 10
- Remainder. The last 12 - 10 = 2 go in shell 3.2 in shell 3
- Write the answer. 2,8,2
Check. 2 + 8 + 2 = 12. ✓
Method. Find the configuration of argon.
- Configuration. Argon has atomic number 18, so its electrons are 2,8,8.2,8,8
- Shells. There are 3 shells.3 shells
- Outer shell. The outer shell is shell 3, which holds 8 electrons.8 in the outer shell
- Write the answer. 3, 8
Check. The outer shell of argon is full. ✓
Watch out
Watch out: the outer shell is not always the one that is filled last. For the first 20 elements, use the rule: shell 1 takes 2, shells 2 and 3 take up to 8 each. Potassium (2,8,8,1) has a fourth shell with one electron.
Exam tip
Exam tip. Check your configuration: the numbers must add up to the atomic number. Write it with commas, as 2,8,1.
Exercise 2A Electron shells and configurations
Method. Recall the first shell.
- Recall. The first electron shell holds up to 2 electrons.holds 2
- Write the answer. 2
Check. Helium has 2 electrons, which fill the first shell. ✓
Method. Recall the second shell.
- Recall. The second shell holds up to 8 electrons.holds 8
- Write the answer. 8
Check. Neon has 2 + 8 = 10 electrons. ✓
Method. Fill the shells in order.
- Shell 1. Shell 1 takes 2 electrons.2
- Shell 2. Shell 2 takes 8 electrons.8
- Shell 3. The last electron goes in shell 3, so 11 - 10 = 1.1
- Write the answer. 2,8,1
Check. 2 + 8 + 1 = 11. ✓
Method. Fill the shells in order.
- Shell 1. Shell 1 takes 2 electrons.2
- Shell 2. Shell 2 takes the other 8 electrons.8
- Write the answer. 2,8
Check. 2 + 8 = 10, the atomic number of neon. ✓
Method. Add the numbers and find the atomic number.
- Add. 2 + 8 + 7 = 17.17
- Name. Element 17 is chlorine.chlorine
- Write the answer. chlorine
Check. Chlorine has seven electrons in its outer shell. ✓
Method. Fill the shells in order.
- Shells 1 and 2. Shells 1 and 2 hold 2 + 8 = 10 electrons.10
- Shell 3. The last 2 electrons go in shell 3.2
- Write the answer. 2,8,2
Check. 2 + 8 + 2 = 12. ✓
Method. Write the configuration of potassium first.
- Configuration. Potassium has atomic number 19, so its arrangement is 2,8,8,1.2,8,8,1
- Count. There are four numbers, so four shells.4 shells
- Write the answer. 4
Check. Potassium is in period 4 of the periodic table. ✓
Method. Write the configuration of argon.
- Configuration. Argon is 2,8,8.2,8,8
- Outer shell. The last number is 8.8
- Write the answer. 8
Check. The outer shell of argon is full. ✓
Method. Write the configuration of carbon.
- Configuration. Carbon has atomic number 6, so it is 2,4.2,4
- Outer shell. The outer shell holds 4 electrons.4
- Write the answer. 4
Check. 2 + 4 = 6. ✓
Method. Add the numbers in the configuration.
- Add. The atomic number equals the total number of electrons: 2 + 8 + 3.2 + 8 + 3 = 13
- Write the answer. 13
Check. Element 13 is aluminium. ✓
Method. Fill the shells, then check the total is 20.
- Shells 1 to 3. Shells 1, 2 and 3 hold 2 + 8 + 8 = 18 electrons.18
- Shell 4. The last 2 electrons go in shell 4.2 in shell 4
- Check. Total = 2 + 8 + 8 + 2 = 20.20
- Write the answer. 2,8,8,2
Check. Calcium is in group 2. ✓
Method. Fill the shells in order.
- Shells 1 and 2. These hold 2 + 8 = 10 electrons.10
- Shell 3. The remaining 15 - 10 = 5 electrons go in shell 3.5
- Write the answer. 2,8,5
Check. 2 + 8 + 5 = 15. ✓
Method. Think about how many electrons each shell can hold.
- Think. For these elements, shell 3 holds up to 8 electrons.up to 8
- Conclude. So after 2,8,8 is full, the 19th electron starts a fourth shell.a fourth shell
- Write the answer. Accept any sentence that says the third shell is full with 8 electrons, so the extra electron goes into a fourth shell.
Check. The total must add up to 19, which the configuration 2,8,8,1 does. ✓
Groups, periods and the periodic table
The periodic table lists the elements in order of atomic number. Each vertical column is a group, and each horizontal row is a period. Elements in the same group have the same number of outer electrons, so they have similar chemical properties. The period number equals the number of electron shells.
| Group | Outer electrons | Name | Example |
|---|---|---|---|
| 1 | 1 | alkali metals | sodium, potassium |
| 2 | 2 | alkaline earth metals | magnesium, calcium |
| 7 | 7 | halogens | chlorine |
| 0 | 8 (helium: 2) | noble gases | neon, argon |
Key ideas
- Periods are rows. The period number equals the number of electron shells.
- Groups are columns. For groups 1, 2 and 3 to 7, the group number equals the number of outer electrons.
- Group 0 (the noble gases) has a full outer shell.
- The table is ordered by atomic number, the number of protons.
Method. Use the configuration to find the period and the group.
- Period. There are 3 shells, so phosphorus is in period 3.period 3
- Group. There are 5 outer electrons, so phosphorus is in group 5.group 5
- Check. The group and period are read from the table.group 5, period 3
- Write the answer. 5, 3
Check. Phosphorus is in group 5, period 3. ✓
Method. Find the column for group 2 and the row for period 3.
- Row. Period 3 is the third row.row 3
- Column. Group 2 is the second column.column 2
- Name. The element in row 3, column 2 is magnesium.magnesium
- Write the answer. magnesium
Check. Magnesium has 2,8,2, which has two outer electrons. ✓
Method. Count the outer electrons.
- Outer shell. The outer shell has 2 electrons.2 electrons
- Group. Outer electrons equal the group number, so the group is 2.group 2
- Write the answer. 2
Check. Calcium (atomic number 20) is in group 2. ✓
Watch out
Watch out: the periods are rows, not columns. A group is a column. Count the rows from the top and the columns from the left.
Exam tip
Exam tip. For groups 1 to 7, the group number tells you the number of outer electrons. For group 0, the outer shell is full.
Exercise 2B Groups and periods
Method. Recall the name of columns.
- Recall. Columns are groups, and rows are periods.group
- Write the answer. group
Check. Elements in the same group have the same outer electrons. ✓
Method. Recall the name of rows.
- Recall. Rows are periods.period
- Write the answer. period
Check. The period number equals the number of shells. ✓
Method. Recall what the atomic number counts.
- Recall. The atomic number is the number of protons.protons
- Write the answer. protons
Check. In a neutral atom, the number of electrons is also the atomic number. ✓
Method. Recall the group of the noble gases.
- Recall. The noble gases are in group 0.group 0
- Write the answer. 0
Check. Helium, neon and argon are all noble gases. ✓
Method. Recall the first group.
- Recall. The alkali metals are the group 1 elements.group 1
- Write the answer. 1
Check. Sodium and potassium are alkali metals. ✓
Method. Count the shells in the configuration of sodium.
- Count. Sodium is 2,8,1, which has 3 shells.3 shells
- Period. The period number equals the number of shells, so period 3.period 3
- Write the answer. 3
Check. Sodium is in the third row. ✓
Method. Recall the group of the halogens.
- Recall. The halogens are group 7.group 7
- Write the answer. 7
Check. Chlorine is a halogen with 7 outer electrons. ✓
Method. Use the group number.
- Group. Calcium is in group 2.group 2
- Outer electrons. For groups 1 and 2, the group number is the number of outer electrons.2
- Write the answer. 2
Check. The configuration 2,8,8,2 ends in 2. ✓
Method. Find the element in the first column of the second row.
- Row and column. Period 2 is the second row, group 1 is the first column.row 2, column 1
- Name. The element is lithium, atomic number 3.lithium
- Write the answer. lithium
Check. Lithium has the configuration 2,1. ✓
Method. Write the configuration first.
- Configuration. Boron has 5 electrons: 2,3.2,3
- Group. It has 3 outer electrons, so it is in group 3.group 3
- Write the answer. 3
Check. Boron is in period 2. ✓
Method. Lithium has 1 outer electron, so look for another element with 1.
- Lithium. Lithium has the configuration 2,1 and is in group 1.group 1
- Sodium. Sodium has 2,8,1, with 1 outer electron, so it is in group 1.group 1
- Others. Neon is in group 0 and carbon is in group 4.not group 1
- Write the answer. sodium
Check. Sodium and lithium both have one outer electron. ✓
Method. Use the period and the group to build the configuration.
- Shells. Period 3 means three shells.three shells
- Outer electrons. Group 5 means 5 outer electrons, so the outer shell has 5.5 in shell 3
- Fill. Shells 1 and 2 hold 2 and 8, so the configuration is 2,8,5.2,8,5
- Write the answer. 2,8,5
Check. Phosphorus has atomic number 15, and 2 + 8 + 5 = 15. ✓
Method. Think about what decides how an element reacts.
- Think. Reactions depend mainly on the outer electrons.outer electrons
- Conclude. Elements in the same group have the same number of outer electrons, so they react similarly.similar reactions
- Write the answer. Accept any sentence that says they have the same number of outer electrons.
Check. Helium and neon are in the same group and both are unreactive. ✓
Predicting properties from the group
Elements in the same group have similar properties. The number of outer electrons decides how an element reacts. Group 1 elements (the alkali metals) have one outer electron and react by losing it. Group 7 elements (the halogens) have seven outer electrons and react by gaining one. The noble gases in group 0 have a full outer shell, so they are very unreactive.
| Group | Outer electrons | Name | Example |
|---|---|---|---|
| 1 | 1 | alkali metals | sodium, potassium |
| 2 | 2 | alkaline earth metals | magnesium, calcium |
| 7 | 7 | halogens | chlorine |
| 0 | 8 (helium: 2) | noble gases | neon, argon |
Key ideas
- Group 1 elements have 1 outer electron.
- Group 7 elements (halogens) have 7 outer electrons.
- Group 0 (noble gases) have a full outer shell, and are unreactive.
- Predictions use the group: an element in the same group will behave in a similar way.
Method. Use the group number for groups 1 and 2.
- Group. Lithium is in group 1.group 1
- Outer electrons. So it has 1 outer electron.1
- Write the answer. 1
Check. Lithium’s configuration is 2,1. ✓
Method. Halogens are in group 7.
- Group. Chlorine is in group 7.group 7
- Outer electrons. So it has 7 outer electrons.7
- Write the answer. 7
Check. The configuration of chlorine is 2,8,7. ✓
Method. Think about the outer shell of argon.
- Configuration. Argon is 2,8,8, so its outer shell is full.full outer shell
- Conclude. A full outer shell is stable, so argon does not need to gain, lose or share electrons.stable
- Write the answer. stable
Check. Noble gases are unreactive because their outer shells are full. ✓
Watch out
Watch out: a prediction from the group is a prediction. It tells you what to expect, and you check it with evidence. Do not say an element will react “because it is in group 1” without linking the outer electrons.
Exam tip
Exam tip. To predict a property, write the group, then the number of outer electrons, then the link to the property.
Exercise 2C Predicting properties from the group
Method. Use the group number.
- Recall. For group 1, the group number is the number of outer electrons.1
- Write the answer. 1
Check. Lithium, sodium and potassium all have one outer electron. ✓
Method. Use the group number.
- Recall. For group 7, the number of outer electrons is 7.7
- Write the answer. 7
Check. Halogens need one more electron to fill the outer shell. ✓
Method. Recall the group of the noble gases.
- Recall. The noble gases are group 0.group 0
- Write the answer. 0
Check. Group 0 is on the far right of the table. ✓
Method. Recall the state of each halogen at room temperature.
- Recall. Fluorine and chlorine are gases, bromine is a liquid, and iodine is a solid.bromine is a liquid
- Write the answer. bromine
Check. Bromine is the only halogen that is a liquid at room temperature. ✓
Method. Recall the halogen gases.
- Recall. Chlorine is a gas at room temperature.chlorine is a gas
- Write the answer. chlorine
Check. Fluorine is also a gas. Accept fluorine too. ✓
Method. Use the group number.
- Recall. For group 2, the number of outer electrons is 2.2
- Write the answer. 2
Check. The configuration of calcium is 2,8,8,2. ✓
Method. Check the outer shell of argon.
- Check. Argon has 2,8,8, so the outer shell has 8 electrons.8 electrons
- Conclude. A full outer shell is stable, so argon is unreactive.stable
- Write the answer. Accept any sentence that says its outer shell is full.
Check. Helium and neon are also unreactive, for the same reason. ✓
Method. Noble gases have a full outer shell.
- Look. The outer shell has 2 electrons, which is not full for this atom.2 is not full
- Decide. So it is not a noble gas, and it is in group 2.no
- Write the answer. no
Check. Calcium has two outer electrons, so it is in group 2. ✓
Method. Use the group number.
- Group. Rubidium is in group 1.group 1
- Outer electrons. So it has 1 outer electron.1
- Write the answer. 1
Check. Rubidium is a group 1 metal, like sodium. ✓
Method. Use the number of outer electrons.
- Outer electrons. The outer shell has 6 electrons.6
- Group. So the element is in group 6.group 6
- Write the answer. 6
Check. Sulfur has 2,8,6. ✓
Method. Compare the outer electrons.
- Compare. Lithium is 2,1 and sodium is 2,8,1, so each has one outer electron.one outer electron
- Conclude. Elements with the same outer electrons react in similar ways.similar ways
- Write the answer. Accept any sentence that says they both have one outer electron.
Check. Sodium is more reactive than lithium, which you will see in Chapter 3. ✓
Method. Compare the outer shells.
- Noble gas. A noble gas has a full outer shell.full
- Halogen. A halogen needs one more electron to fill its outer shell.one more electron
- Conclude. So the halogen is much more likely to react.more likely
- Write the answer. Accept any sentence that says the noble gas has a full outer shell, so it does not need to gain or lose electrons.
Check. A full outer shell does not need changing. ✓
The development of the periodic table
Early tables ordered the elements by relative atomic mass. Mendeleev noticed that elements with similar properties appeared at regular intervals. He left gaps for elements he thought had not yet been discovered, and he predicted their properties. Some elements were put in an order that did not match their mass, so that they fitted with the elements that had similar properties.
| Point | What happened | Detail |
|---|---|---|
| 1869 | Mendeleev | arranged by relative atomic mass; gaps left for undiscovered elements |
| Tellurium and iodine | swapped | tellurium (Ar 127.6) is placed before iodine (Ar 126.9) so that iodine fits the halogens |
| Gallium and germanium | predicted | Mendeleev predicted elements with the properties that these two later showed |
| Noble gases | added later | discovered after the table was made, so they needed a new group |
| Modern table | atomic number | ordered by the number of protons, which fixes most of the problems |
Key ideas
- Mendeleev arranged the elements by relative atomic mass and left gaps for undiscovered elements.
- He predicted properties for missing elements, and later discoveries (such as gallium and germanium) supported him.
- Noble gases were discovered later, and were added as a new group.
- The modern table is ordered by atomic number, which fixes the problems with the order of mass.
Method. Compare the masses and the properties.
- Masses. Tellurium has a relative atomic mass of 127.6, and iodine is 126.9.Te 127.6, I 126.9
- Properties. Iodine has the properties of a halogen, so it had to go in the group 7 column.halogen
- Conclude. So the order was changed to fit the properties.order changed
- Write the answer. So that iodine fitted with the halogens, which have similar properties.
Check. Mendeleev chose properties over relative atomic mass. ✓
Method. Think about the pattern in the table.
- Pattern. Mendeleev saw a pattern of properties at regular intervals.pattern
- Gap. A missing element would fit the pattern, so a gap was left for it.gap left
- Write the answer. Accept any element that was not yet discovered in 1869 with a reason about the pattern of properties.
Check. Gallium and germanium were the elements that filled the gaps. ✓
Method. Compare the atomic numbers.
- Atomic numbers. Argon has atomic number 18 and potassium has atomic number 19.18 and 19
- Order. The table is ordered by atomic number, so the smaller number comes first.argon first
- Write the answer. argon
Check. Argon is in group 0 and potassium is in group 1. ✓
Watch out
Watch out: the modern table is ordered by atomic number, not relative atomic mass. Argon is placed before potassium, even though its relative atomic mass is larger.
Exam tip
Exam tip. When you explain Mendeleev’s table, mention the gaps and the predicted properties. Do not say that Mendeleev knew the atomic number.
Exercise 2D Development of the periodic table
Method. Recall the scientist.
- Recall. Dmitri Mendeleev arranged the elements in 1869.Mendeleev
- Write the answer. Mendeleev
Check. Mendeleev’s table is the basis of the modern table. ✓
Method. Recall the first ordering.
- Recall. Mendeleev ordered the elements by relative atomic mass.relative atomic mass
- Write the answer. relative atomic mass
Check. Later, the table was ordered by atomic number. ✓
Method. Think about the pattern of properties.
- Think. The pattern showed that some elements were missing.missing
- Conclude. So he left gaps for elements that had not yet been discovered.not yet discovered
- Write the answer. for elements not yet discovered
Check. Mendeleev predicted their properties. ✓
Method. Recall the elements that filled his gaps.
- Recall. Gallium was one of the elements Mendeleev predicted.gallium
- Write the answer. gallium
Check. Germanium is another accepted answer. ✓
Method. Recall the order of the modern table.
- Recall. The modern table is ordered by atomic number.atomic number
- Write the answer. atomic number
Check. Atomic number is the number of protons. ✓
Method. Use the atomic number.
- Recall. Atomic number 17 is chlorine.chlorine
- Write the answer. chlorine
Check. Chlorine has 2,8,7. ✓
Method. Compare the two relative atomic masses.
- Compare. Tellurium is 127.6 and iodine is 126.9.127.6 > 126.9
- Write the answer. tellurium
Check. Tellurium is heavier but comes before iodine in the table. ✓
Method. Think about when they were found.
- Think. The noble gases were not known when Mendeleev arranged his table.not known
- Conclude. They were added as a new group after they were discovered.added later
- Write the answer. Accept any sentence that says they were discovered after Mendeleev made his table.
Check. Argon was discovered in 1894, after Mendeleev’s table. ✓
Method. Compare the two orders.
- Atomic number. Each element has a different atomic number, which is a whole number.unique whole number
- Pairs. The order no longer puts argon and potassium the wrong way round.no reversed pairs
- Write the answer. Accept any sentence that says atomic number is unique to each element and avoids the reversed pairs.
Check. Relative atomic mass is an average, so it does not always follow the pattern. ✓
Method. Think about the pattern.
- Think. Elements with similar properties appear at regular intervals.regular intervals
- Conclude. A missing element in the pattern can be predicted from its neighbours.predicted
- Write the answer. Accept any sentence that says the periodic pattern of properties showed a missing element.
Check. Predictions are tested when the element is found. ✓
Metals, non-metals, transition metals and noble gases
Metals are on the left and in the middle of the periodic table. Non-metals are on the right. Metals are usually shiny, conduct electricity and have higher melting points than non-metals. The transition metals are a block of metals between groups 2 and 3, including iron, copper and nickel. They are often hard, dense, and form coloured compounds. Many of them are useful catalysts.
Noble gases in group 0 have full outer shells. They are very unreactive, so they are used in lamps and balloons. Helium, neon and argon are examples.
| Property | Metals | Non-metals |
|---|---|---|
| position | left and centre of the table | right of the table |
| melting point (typical) | usually high | usually low |
| conduct electricity | yes, usually | no (carbon graphite is an exception) |
| oxides | usually alkaline or basic | usually acidic |
| outer electrons (typical) | usually 1 to 3 | usually 4 to 8 |
| Property | Transition metals | Group 1 metals |
|---|---|---|
| position | block between groups 2 and 3 | group 1 |
| density and hardness | usually high and hard | low density, soft |
| melting point | usually high | low |
| coloured compounds | yes, often | no |
| catalyst | often (for example iron in the Haber process) | not usually |
Key ideas
- Metals are on the left and centre; non-metals are on the right.
- Transition metals sit in the block between groups 2 and 3.
- Transition metals are often hard, dense, have high melting points, form coloured compounds and can act as catalysts.
- Noble gases have full outer shells, so they are unreactive.
Method. Use the position of iron on the table.
- Position. Iron is a transition metal in the middle of the table.middle
- Decide. Elements in the left and middle of the table are metals.metal
- Write the answer. metal
Check. Iron is a metal used in steel. ✓
Method. Compare the two tables of properties.
- Compare. Transition metals are often hard and dense, and group 1 metals are soft.hard, dense
- Choose. Transition metals often form coloured compounds, and group 1 metals do not.coloured compounds
- Write the answer. coloured compounds
Check. Accept also: high melting point, or a catalyst. ✓
Method. Think about the outer shell of helium.
- Configuration. Helium has the configuration 2, so its only shell is full.full shell
- Conclude. A full outer shell is stable, so helium does not react.stable
- Write the answer. its outer shell is full
Check. Noble gases have full outer shells. ✓
Watch out
Watch out: a transition metal is not in group 1. It is in the block between groups 2 and 3, and it is a separate group of metals.
Exam tip
Exam tip. When a question asks for a property of transition metals, give a property that is typical, such as coloured compounds or use as a catalyst.
Exercise 2E Metals, non-metals, transition metals and noble gases
Method. Recall where the metals are.
- Recall. Metals are on the left and in the centre of the table.left
- Write the answer. left
Check. Non-metals are on the right. ✓
Method. Recall where the non-metals are.
- Recall. Non-metals are on the right of the table.right
- Write the answer. right
Check. Hydrogen is a special case, but it is not needed here. ✓
Method. Recall the properties of copper.
- Recall. Copper is a shiny metal that conducts electricity.metal
- Write the answer. metal
Check. Copper is a transition metal. ✓
Method. Recall a non-metal gas.
- Recall. Oxygen is a non-metal gas at room temperature.oxygen
- Write the answer. oxygen
Check. Accept nitrogen, chlorine, neon or argon. ✓
Method. Recall the block.
- Recall. The transition metals are between groups 2 and 3.transition metals
- Write the answer. transition metals
Check. Iron and copper are transition metals. ✓
Method. Recall typical properties.
- Recall. Transition metals are often hard, dense and have high melting points.hard, dense
- Also. They often form coloured compounds and can act as catalysts.coloured compounds
- Write the answer. Accept any of: hard, dense, high melting point, coloured compounds, catalyst.
Check. Iron is used as a catalyst in the Haber process. ✓
Method. Find iron on the table.
- Find. Iron is in the block between groups 2 and 3.transition metal
- Decide. So iron is a transition metal.yes
- Write the answer. yes
Check. Iron is also used in steel. ✓
Method. Write the configuration of helium.
- Configuration. Helium has 2 electrons in one shell.2
- Outer shell. The outer shell is the first shell, which is full with 2.2
- Write the answer. 2
Check. The first shell holds up to 2 electrons. ✓
Method. Recall a use of a noble gas.
- Recall. Argon is used in light bulbs because it does not react with the filament.argon in bulbs
- Also. Helium is used in balloons because it is light and does not react.helium in balloons
- Write the answer. Accept any one of: lamps, balloons, a shield for welding, a protective gas.
Check. A noble gas is chosen because it does not react. ✓
Method. Check the position of each element.
- Sulfur. Sulfur is a non-metal on the right.non-metal
- Sodium. Sodium is a group 1 metal on the left.metal
- Chlorine. Chlorine is a non-metal (a halogen).non-metal
- Write the answer. sodium
Check. Sodium is a soft, shiny metal that reacts with water. ✓
Method. Find its group.
- Group. Six outer electrons means group 6.group 6
- Decide. Elements on the right of the table are non-metals.non-metal
- Write the answer. non-metal
Check. Sulfur has the configuration 2,8,6. ✓
Method. Think about the electrons.
- Think. The noble gases have full outer shells.full
- Conclude. A full outer shell is stable, so the atoms do not need to gain, lose or share electrons.stable
- Write the answer. Accept any sentence that says they have a full outer shell, which is stable.
Check. Helium has two electrons, which fill its only shell. ✓
Method. Find where transition metals are.
- Find. Transition metals are in a block between groups 2 and 3.between groups 2 and 3
- Conclude. So they are not in group 1.not group 1
- Write the answer. Accept any sentence that says transition metals form a block between groups 2 and 3.
Check. Group 1 contains alkali metals, which are soft and very reactive. ✓
Chapter summary
| Skill | Method |
|---|---|
| Shells | The first holds 2 electrons; the second and third hold up to 8 each (first 20 elements). |
| Electronic configuration | The number of electrons in each shell; the numbers add up to the atomic number. |
| Periods and groups | Periods are rows (number = number of shells); groups are columns (number = outer electrons for groups 1 to 7). |
| Mendeleev | Ordered by relative atomic mass; left gaps and predicted missing elements. |
| Modern table | Ordered by atomic number, the number of protons. |
| Metals and non-metals | Metals on the left and centre; non-metals on the right. |
| Transition metals | A block between groups 2 and 3; hard, dense, coloured compounds, often catalysts. |
| Noble gases | Group 0; full outer shells; very unreactive. |
Can you…?
- I can write the electronic configuration of the first 20 elements
- I can find the group and period of an element from its configuration
- I can predict properties from the number of outer electrons
- I can explain how Mendeleev arranged the elements and why the modern table is ordered by atomic number
- I can compare metals, non-metals, transition metals and noble gases
Key terms
- electron shell
- a layer of electrons around the nucleus of an atom
- electronic configuration
- the number of electrons in each shell of an atom, such as 2,8,1
- group
- a vertical column in the periodic table; elements in it have the same number of outer electrons
- period
- a horizontal row in the periodic table; its number is the number of electron shells
- outer electrons
- the electrons in the outermost shell of an atom
- transition metals
- the block of metals between groups 2 and 3
- noble gases
- the group 0 elements, which have full outer shells and are unreactive
- relative atomic mass
- the average mass of an atom of an element, compared with carbon-12
Exercise 2Z Check-up
Method. Fill the shells in order.
- Shells. Shell 1 takes 2, shell 2 takes 8, the rest (7) go in shell 3.2,8,7
- Write the answer. 2,8,7
Check. 2 + 8 + 7 = 17. ✓
Method. The period number equals the number of shells.
- Recall. Three shells means period 3.period 3
- Write the answer. 3
Check. Sodium is in period 3. ✓
Method. For groups 1 to 7, outer electrons equal the group number.
- Recall. Six outer electrons means group 6.group 6
- Write the answer. 6
Check. Oxygen is in group 6. ✓
Method. Recall the element with atomic number 20.
- Recall. Calcium has atomic number 20.calcium
- Write the answer. calcium
Check. Calcium has 2,8,8,2. ✓
Method. Recall the scientist.
- Recall. Mendeleev left gaps for undiscovered elements.Mendeleev
- Write the answer. Mendeleev
Check. He predicted the properties of the missing elements. ✓
Method. Recall the group of the halogens.
- Recall. Halogens are group 7.group 7
- Write the answer. 7
Check. Halogens have 7 outer electrons. ✓
Method. Recall the group of the noble gases.
- Recall. The noble gases are in group 0.group 0
- Write the answer. 0
Check. Argon is in group 0. ✓
Method. Use the row and column.
- Row and column. Period 2 is the second row; group 2 is the second column.row 2, column 2
- Name. The element is beryllium, atomic number 4.beryllium
- Write the answer. beryllium
Check. Beryllium has 2,2. ✓
Method. Write the configuration, then read the group and period.
- Configuration. Phosphorus is 2,8,5.2,8,5
- Read. Five outer electrons means group 5; three shells means period 3.group 5, period 3
- Write the answer. 5, 3
Check. 2 + 8 + 5 = 15. ✓
Method. Compare the outer electrons.
- Compare. Sodium is 2,8,1 and potassium is 2,8,8,1.one outer electron
- Conclude. Elements with the same number of outer electrons react similarly.similar
- Write the answer. Accept any sentence that says they both have one outer electron.
Check. Both are group 1 metals. ✓
Total 21 marks. Allow about 21 minutes.
Exercise 2X Exam-style questions
Method. Fill the shells in order.
- Shells 1 to 3. Shells 1, 2 and 3 hold 2 + 8 + 8 = 18 electrons.18
- Shell 4. The last electron goes in shell 4.1 in shell 4
- Write the answer. 2,8,8,1
Check. 2 + 8 + 8 + 1 = 19. ✓
Method. Read the outer electrons and the number of shells.
- Group. One outer electron means group 1.group 1
- Period. Three shells means period 3.period 3
- Write the answer. 1, 3
Check. This is sodium, which is in group 1, period 3. ✓
Method. Find the element in the seventh column of row 2.
- Find. Row 2 and column 7 is fluorine, atomic number 9.fluorine
- Write the answer. fluorine
Check. Fluorine has 2,7. ✓
Method. Recall the scientist.
- Recall. Mendeleev predicted properties for the gaps.Mendeleev
- Write the answer. Mendeleev
Check. Gallium was predicted by him. ✓
Method. Compare argon and potassium.
- Atomic numbers. Argon is 18 and potassium is 19.18 < 19
- Conclude. Ordering by atomic number puts argon before potassium, so the elements fit their groups.argon first
- Write the answer. Accept any sentence that says atomic number fixes the order, so argon (18) comes before potassium (19).
Check. Relative atomic mass would put potassium first, which does not fit the groups. ✓
Method. Recall where each type is.
- Metals. Metals are on the left and in the centre.left and centre
- Non-metals. Non-metals are on the right.right
- Write the answer. Accept any sentence that says metals are on the left and centre, and non-metals on the right.
Check. Carbon and sulfur are non-metals on the right. ✓
Method. Write the configuration of neon.
- Configuration. Neon is 2,8.2,8
- Conclude. Its outer shell has 8 electrons, which is full and stable.full and stable
- Write the answer. Accept any sentence that says its outer shell is full with 8 electrons.
Check. A full outer shell does not need to change. ✓
Method. Recall typical properties.
- List. Transition metals are often hard and dense, with high melting points.hard, dense
- Also. They often form coloured compounds and can be catalysts.coloured compounds
- Write the answer. Accept any two of: hard, dense, high melting point, coloured compounds, catalyst.
Check. Iron is a transition metal and a catalyst. ✓
Method. Use the period to find the shells and the group to find the outer electrons.
- Shells. Period 4 means four shells.four shells
- Outer electrons. Group 2 means 2 outer electrons.2 in shell 4
- Fill. Shells 1 to 3 hold 2, 8 and 8, so the arrangement is 2,8,8,2.2,8,8,2
- Write the answer. 2,8,8,2
Check. The total 2 + 8 + 8 + 2 = 20, which is calcium. ✓
Method. Use the outer electrons.
- Outer electrons. All group 1 elements have one outer electron.one outer electron
- Link. Reactions depend on the outer electrons, so they react in similar ways.similar ways
- Conclude. This is why group 1 is a family of elements.family
- Write the answer. Accept any answer that says they all have one outer electron, so they react in a similar way.
Check. Lithium, sodium and potassium are all group 1 metals. ✓