Reactivity of metals and halogens
By the end of this chapter you will be able to
- Use the reactivity series to say which metal is more reactive
- Predict whether a displacement reaction happens, and write a word equation for it
- Describe how Group 1 metals react with water, and how the reactivity changes down the group
- Describe the colours, states and melting points of the halogens, and their reactivity
- Explain displacement of halide ions, and [H] explain the trends using electron shells
You should already know
- Groups and outer electrons (Chapter 2)
- The atomic number and electron shells (Chapters 1 and 2)
Where this leads
- Ionic bonding of Group 1 and Group 7 ions (Chapter 4)
- Acids, alkalis and salts (Chapter 10)
- Electrolysis and displacement (Chapter 11)
GCSE Chemistry. Content follows the GCSE (9-1) subject content for England (Edexcel and AQA). Content references: Use the reactivity series of metals (potassium to gold) to predict displacement reactions, Describe reactions of metals with water and dilute acid, and the products, Carry out a displacement practical with metals and metal salt solutions, safely, Describe the trend in reactivity of Group 1 metals, and their reactions with water, Describe the trend in properties and reactivity of Group 7 halogens, and displacement reactions, [H] Explain the trends in reactivity using electron shells and outer electrons.
Exercise P Do you remember?
Method. Recall the first group.
- Recall. The alkali metals are group 1.group 1
- Write the answer. 1
Check. Sodium is in group 1. ✓
Method. Use the group number for group 7.
- Recall. Group 7 elements have 7 outer electrons.group 7 = 7
- Write the answer. 7
Check. Chlorine is 2,8,7. ✓
Method. Recall the symbol.
- Recall. The symbol for potassium is K.K
- Write the answer. K
Check. Potassium is from the Latin kalium. ✓
Method. Recall the gas.
- Recall. Metals and dilute acids produce hydrogen gas.hydrogen
- Write the answer. hydrogen
Check. Hydrogen is tested with a lighted splint in Chapter 17. ✓
Method. Multiply first, then add.
- Multiply. 2 x 3 = 6.6
- Add. 6 + 4 = 10.10
- Write the answer. 10
Check. Adding first would give 14, which is wrong. ✓
The reactivity series and reactions of metals
The reactivity series lists metals from the most reactive to the least reactive. Potassium is the most reactive in this list, and gold is the least. The more reactive a metal, the more readily it loses electrons to form positive ions. Reactive metals react faster with water and acids, and they form more stable compounds.
Metals above copper react with dilute acid to give a salt and hydrogen. Copper, silver and gold do not react with dilute acid.
| Metal | Cold water | Dilute acid |
|---|---|---|
| potassium, sodium, lithium | vigorous reaction; hydrogen forms (teacher demonstration only) | very vigorous (not for pupils) |
| calcium | steady reaction, hydrogen forms | vigorous |
| magnesium | very slow | vigorous |
| aluminium, zinc, iron | almost no reaction | reacts, hydrogen forms |
| copper, silver, gold | no reaction | no reaction |
Key ideas
- The reactivity series ranks metals from most reactive (potassium) to least reactive (gold).
- A metal above copper in the series (and so above hydrogen) reacts with dilute acid to give a salt and hydrogen.
- Copper, silver and gold do not react with dilute acid.
- Potassium, sodium and lithium react with cold water; calcium reacts steadily; magnesium reacts very slowly with cold water.
Method. Find both metals in the reactivity series.
- Find. Zinc is above copper in the reactivity series.zinc above copper
- Decide. So zinc is more reactive.zinc
- Write the answer. zinc
Check. Zinc reacts with dilute acid, and copper does not. ✓
Method. Recall what metals above copper produce with acid.
- Recall. Magnesium is above copper, so it reacts with dilute acid.reacts
- Product. Metals with dilute acid give a salt and hydrogen.hydrogen
- Write the answer. hydrogen
Check. Magnesium chloride is the salt. Hydrogen is the gas. ✓
Method. Use the results table.
- Look. Calcium reacts steadily with cold water, and magnesium only very slowly.calcium steady
- Name. So calcium is the metal.calcium
- Write the answer. calcium
Check. Potassium and sodium react more vigorously. ✓
Watch out
Watch out: the reactivity series is about reactivity, not about the price or the density of a metal. Use the order only to predict reactions.
Exam tip
Exam tip. When you compare two metals, say which is higher in the reactivity series, not which is “stronger”.
Exercise 3A The reactivity series and reactions of metals
Method. Read the top of the series.
- Read. Potassium is at the top, so it is the most reactive.potassium
- Write the answer. potassium
Check. Gold is at the bottom. ✓
Method. Read the bottom of the series.
- Read. Gold is at the bottom, so it is the least reactive.gold
- Write the answer. gold
Check. Gold does not tarnish easily. ✓
Method. Find zinc and copper, then read the metal between them.
- Find. Zinc, iron and copper are in that order.zinc, iron, copper
- Read. So iron is between them.iron
- Write the answer. iron
Check. Iron is more reactive than copper. ✓
Method. Compare the positions in the series.
- Compare. Magnesium is above zinc.above
- Decide. So magnesium is more reactive.more
- Write the answer. more
Check. Magnesium reacts with dilute acid more vigorously than zinc. ✓
Method. Recall the symbol.
- Recall. The symbol for sodium is Na.Na
- Write the answer. Na
Check. Sodium is the second most reactive metal in the list. ✓
Method. Use the results table.
- Read. Calcium reacts steadily with cold water, releasing hydrogen.calcium
- Write the answer. calcium
Check. Magnesium reacts very slowly with cold water. ✓
Method. Look for the metals below hydrogen in the series.
- Read. Copper is below hydrogen, so it does not react with dilute acid.copper
- Write the answer. copper
Check. Silver and gold also do not react with dilute acid. ✓
Method. Recall the product of metal and acid.
- Recall. Metals above copper react with dilute acid to give a salt and hydrogen.hydrogen
- Write the answer. hydrogen
Check. Zinc chloride is the salt formed. ✓
Method. The metal gives the first part of the salt name, and the acid gives the second.
- Metal. Magnesium is the metal.magnesium
- Acid. Hydrochloric acid gives chloride.chloride
- Salt. So the salt is magnesium chloride.magnesium chloride
- Write the answer. magnesium chloride
Check. The formula is MgCl2. ✓
Method. Use the series, with the most reactive first.
- Magnesium. Magnesium is above zinc.magnesium first
- Zinc. Zinc is above copper.zinc next
- Copper. Copper is the least reactive of the three.copper last
- Write the answer. magnesium, zinc, copper
Check. Magnesium, zinc, copper is the order in the series. ✓
Method. Think about where gold is in the series.
- Think. Gold is at the bottom of the series, the least reactive metal.least reactive
- Conclude. So it does not react with air or water, and it keeps its shine.keeps its shine
- Write the answer. Accept any sentence that says gold is unreactive, so it does not corrode or tarnish.
Check. Gold does not react with dilute acid. ✓
Method. Compare gold with hydrogen.
- Gold. Gold is below hydrogen in the reactivity series.below hydrogen
- Conclude. So gold does not react with dilute acid, even though it is a metal.does not react
- Write the answer. Accept any sentence that says gold is below hydrogen in the series, so it does not react with dilute acid.
Check. Being a metal is not enough; the position in the series matters. ✓
Method. Check whether each metal reacts with acid.
- Calcium. Calcium is above hydrogen, so it reacts with dilute acid.reacts
- Copper. Copper is below hydrogen, so it does not react.no reaction
- Decide. So calcium reacts more vigorously.calcium
- Write the answer. calcium
Check. Calcium is more reactive than copper. ✓
Displacement reactions: required practical
A displacement reaction happens when a more reactive metal takes the place of a less reactive metal in a compound. In the practical, pupils place a clean piece of a metal into a dilute copper sulfate solution. A reaction shows as a brown solid of copper forming, and the blue colour of the solution fading. Magnesium, zinc and iron displace copper; copper does not displace magnesium.
| Mixture | Observation | Conclusion |
|---|---|---|
| Mg + CuSO4 | Copper forms; the blue colour fades | magnesium is more reactive than copper |
| Zn + CuSO4 | Copper forms; the blue colour fades | zinc is more reactive than copper |
| Fe + CuSO4 | Copper forms slowly | iron is more reactive than copper |
| Cu + MgSO4 | No reaction | copper is less reactive than magnesium |
Try it (with your teacher). Required practical: displacement of metals in copper sulfate solution. Use a fixed volume of dilute copper sulfate in each tube, and the same size of each metal piece. Wear goggles and gloves, keep copper sulfate off your skin, and wash your hands at the end. Copper sulfate is harmful if swallowed. Put the solids in the waste container that your teacher gives you. Record the colour change and the solid formed.
Key ideas
- A more reactive metal displaces a less reactive metal from its compound.
- Copper forms as a brown solid; the blue colour of copper sulfate fades when zinc or magnesium is used.
- Fair test: keep the volume, the concentration and the size of the metal pieces the same.
- Word equation: magnesium + copper sulfate -> magnesium sulfate + copper.
Method. Compare zinc and copper in the series.
- Compare. Zinc is above copper in the reactivity series.zinc above copper
- Decide. So zinc displaces copper, and a reaction happens.yes
- Write the answer. yes
Check. The copper forms as a brown solid. ✓
Method. Magnesium takes the place of copper in the compound.
- Reactants. Magnesium and copper sulfate.magnesium + copper sulfate
- Products. Magnesium takes the sulfate, so the products are magnesium sulfate and copper.magnesium sulfate + copper
- Write the answer. magnesium sulfate and copper
Check. Copper is the solid that forms. ✓
Method. Compare copper and magnesium in the series.
- Compare. Copper is below magnesium, so it is less reactive.copper below magnesium
- Observe. Copper cannot displace magnesium, so no reaction is seen.no reaction
- Write the answer. no reaction
Check. The solution stays the same colour. ✓
Watch out
Watch out: the displaced metal is the less reactive one. In magnesium + copper sulfate, copper is displaced, so copper is the product that forms as a solid.
Exam tip
Exam tip. For a displacement practical, write the three things you control (volume, concentration, size of metal), and the one thing you measure or observe (the colour change).
Exercise 3B Displacement reactions
Method. Recall the colour of copper sulfate.
- Recall. Copper sulfate solution is blue.blue
- Write the answer. blue
Check. The blue colour fades when copper is displaced. ✓
Method. Look at the equation.
- Look. Magnesium takes the place of copper in the compound.takes the place
- Name. So copper is displaced.copper
- Write the answer. copper
Check. Copper forms as a brown solid. ✓
Method. Recall the solid formed.
- Recall. The copper that forms is a brown solid.brown
- Write the answer. brown
Check. Copper is a reddish-brown solid. ✓
Method. Think about the zinc sulfate that forms.
- Think. Zinc sulfate solution is colourless, so the blue fades.colourless
- Write the answer. colourless
Check. The blue of copper sulfate is gone. ✓
Method. Recall the compound made from magnesium.
- Recall. Magnesium takes the sulfate, forming magnesium sulfate.magnesium sulfate
- Write the answer. magnesium sulfate
Check. Magnesium sulfate is a colourless solution. ✓
Method. Compare copper and magnesium in the series.
- Compare. Copper is less reactive than magnesium.less reactive
- Decide. So copper cannot displace magnesium.no
- Write the answer. no
Check. Nothing changes in the solution. ✓
Method. Think about the risk of splashes.
- Think. Copper sulfate can splash into the eyes.eyes
- Decide. So goggles must be worn.goggles
- Write the answer. goggles
Check. Gloves are also needed. ✓
Method. Think about what makes the test fair.
- Think. Only the metal should change, so the other variables are kept the same.only the metal changes
- Name. For example, the volume of copper sulfate solution is kept the same.volume
- Write the answer. Accept volume, concentration or size of the metal.
Check. The changing variable is the type of metal. ✓
Method. Compare zinc and magnesium in the series.
- Compare. Magnesium is above zinc, so it is more reactive.magnesium more reactive
- Decide. Zinc is less reactive, so it cannot displace magnesium.no
- Write the answer. no
Check. Only the more reactive metal displaces the less reactive one. ✓
Method. Check the order in the series.
- Check. Magnesium is above zinc, so it is more reactive.more reactive
- Decide. So magnesium displaces zinc.yes
- Write the answer. yes
Check. Zinc metal forms and the zinc sulfate solution is formed. ✓
Method. Magnesium takes the place of zinc.
- Products. Magnesium forms magnesium sulfate, and zinc is displaced.magnesium sulfate and zinc
- Write the answer. magnesium sulfate and zinc
Check. Magnesium is more reactive, so it replaces zinc. ✓
Method. Use the reactivity series.
- Compare. Iron is below magnesium in the series.below magnesium
- Conclude. So iron is less reactive and cannot displace magnesium.cannot displace
- Write the answer. Accept any sentence that says iron is less reactive than magnesium, so it cannot displace magnesium.
Check. Being a metal is not enough; the position in the series matters. ✓
Method. Think about what changes between the tubes.
- Think. Only the metal should be different between the tubes.only the metal
- Conclude. Using the same volume keeps the test fair.fair
- Write the answer. Accept any sentence that says it keeps the test fair.
Check. A fair test changes one thing only. ✓
Group 1: the alkali metals
The alkali metals are the group 1 elements: lithium, sodium and potassium. Each has one outer electron. When an alkali metal reacts with water, it forms a metal hydroxide and hydrogen. The hydroxide dissolves, making the solution alkaline. Going down group 1, the reactions become more vigorous, so reactivity increases down the group.
| Alkali metal | Symbol | Atomic number | Reaction with water (teacher demonstration) |
|---|---|---|---|
| Lithium | Li | 3 | fizzes steadily |
| Sodium | Na | 11 | melts and moves about, faster |
| Potassium | K | 19 | very vigorous; hydrogen may ignite |
Key ideas
- Alkali metals have one outer electron.
- Reactivity increases down group 1: potassium is more reactive than sodium, which is more reactive than lithium.
- The word equation: metal + water -> metal hydroxide + hydrogen.
- Alkali metal reactions with water are done by a teacher only. They are vigorous and can be dangerous.
Method. Use the general pattern for group 1 with water.
- Reactants. Sodium and water.sodium + water
- Products. Sodium forms sodium hydroxide, and hydrogen is released.sodium hydroxide + hydrogen
- Write the answer. sodium hydroxide and hydrogen
Check. Sodium hydroxide is a strong alkali. ✓
Method. Reactivity increases down group 1.
- Position. Potassium is below lithium in group 1.below
- Decide. So potassium is more reactive.potassium
- Write the answer. potassium
Check. Potassium reacts more vigorously with water. ✓
Method. Name the metal hydroxide.
- Metal. The metal is lithium.lithium
- Hydroxide. Lithium with water forms lithium hydroxide.lithium hydroxide
- Write the answer. lithium hydroxide
Check. The solution is alkaline. ✓
Watch out
Watch out: a group 1 metal reacts with water to make a hydroxide (for example sodium hydroxide), not an acid. The solution made is alkaline.
Exam tip
Exam tip. When you describe a trend, say the direction: reactivity increases down group 1. Do not write “gets bigger” without saying what changes.
Exercise 3C Group 1: the alkali metals
Method. Recall the first group.
- Recall. The alkali metals are group 1.1
- Write the answer. 1
Check. Lithium, sodium and potassium are alkali metals. ✓
Method. Use the group number.
- Recall. For group 1, the number of outer electrons is 1.1
- Write the answer. 1
Check. Potassium is 2,8,8,1. ✓
Method. Recall the symbol.
- Recall. The symbol for lithium is Li.Li
- Write the answer. Li
Check. Li has a capital L and a small i. ✓
Method. Use the atomic number.
- Recall. Atomic number 11 is sodium.sodium
- Write the answer. sodium
Check. Sodium is 2,8,1. ✓
Method. Recall the product.
- Recall. The metal forms a metal hydroxide, and hydrogen is released.hydroxide
- Write the answer. hydroxide
Check. For example, sodium hydroxide. ✓
Method. Compare the positions in group 1.
- Position. Potassium is below sodium.below
- Decide. So potassium is more reactive.more
- Write the answer. more
Check. Reactivity increases down group 1. ✓
Method. Use the pattern for group 1 with water.
- Products. Lithium forms lithium hydroxide, and hydrogen is released.lithium hydroxide + hydrogen
- Write the answer. lithium hydroxide and hydrogen
Check. Lithium is the least reactive of the three. ✓
Method. Find the metal lowest in group 1.
- Find. Potassium is the lowest of these three in group 1.lowest
- Decide. So it is the most reactive.potassium
- Write the answer. potassium
Check. Potassium is more reactive than sodium, which is more reactive than lithium. ✓
Method. Think about the reaction.
- Think. Alkali metals react vigorously with water.vigorously
- Conclude. So they are stored away from water, and only a teacher handles them.teacher only
- Write the answer. Accept any reason that says they react vigorously with water.
Check. Alkali metals are stored in oil in the lab. ✓
Method. Reactivity increases down group 1.
- Position. Rubidium is below potassium.below
- Predict. So rubidium reacts more vigorously than potassium.more vigorously
- Write the answer. more vigorously
Check. Predictions for group 1 follow the trend. ✓
Method. Think about the shells.
- Shells. Each element down the group has an extra shell.extra shell
- Conclude. The outer electron is further from the nucleus, so it is lost more easily.lost more easily
- Write the answer. Accept any sentence that says the outer electron is further from the nucleus, so it is lost more easily.
Check. This explanation is developed further in section 3.5. ✓
Method. Think about the hazard.
- Think. Potassium and sodium react violently with water.violent
- Conclude. So a teacher must do it with safety equipment and a safe amount of metal.teacher
- Write the answer. Accept any reason that says the reaction is vigorous and can be dangerous.
Check. Pupils watch a teacher demonstration. ✓
Method. Compare lithium and potassium.
- Compare. All group 1 metals react with water to form a hydroxide and hydrogen.same products
- Compare speed. The speed differs: potassium is much faster than lithium.speed differs
- Write the answer. no, reactions differ in speed
Check. The products are the same, but the speed is different. ✓
Group 7: the halogens
The halogens are group 7: fluorine, chlorine, bromine and iodine. Going down the group, their melting points increase, so they change from gases, to liquids, to solids. Their reactivity decreases down the group. A more reactive halogen displaces a less reactive halide ion from solution.
| Halogen | Symbol | Colour and state at room temperature | Melting point (degrees C) |
|---|---|---|---|
| Fluorine | F | pale yellow gas | -220 |
| Chlorine | Cl | green gas | -101 |
| Bromine | Br | red-brown liquid | -7 |
| Iodine | I | grey-black solid | 114 |
| Astatine (predicted) | At | dark solid (predicted) | higher than iodine (predicted) |
Key ideas
- Halogens are diatomic molecules: Cl2, Br2, I2.
- Melting points increase down group 7; fluorine is a pale yellow gas, iodine is a grey-black solid.
- Reactivity decreases down group 7: fluorine is the most reactive.
- Displacement: chlorine displaces bromide and iodide ions; bromine displaces iodide ions.
Try it (with your teacher). Teacher demonstration only: a teacher may add a little chlorine water to potassium bromide solution. Chlorine is toxic, so pupils watch from a safe distance in a fume cupboard. The solution turns orange-brown because bromine is displaced.
Method. Use the table.
- Look. Fluorine is a pale yellow gas at room temperature.pale yellow gas
- Name. So the halogen is fluorine.fluorine
- Write the answer. fluorine
Check. Fluorine has the lowest melting point of the group. ✓
Method. A more reactive halogen displaces a less reactive one.
- Compare. Chlorine is above bromine in group 7, so it is more reactive.more reactive
- Displace. Chlorine displaces bromine from potassium bromide.bromine forms
- Write the answer. bromine
Check. Potassium chloride is the other product. ✓
Method. Use the melting point and state.
- Look. Iodine has the highest melting point of the four.highest melting point
- Name. It is a grey-black solid at room temperature.iodine
- Write the answer. iodine
Check. Iodine melts at 114 degrees C. ✓
Watch out
Watch out: a more reactive halogen displaces a less reactive halide ion, not a metal. Iodide is displaced by bromine, and bromide is displaced by chlorine.
Exam tip
Exam tip. For halogen displacement, say which halogen is more reactive (the one higher up group 7) and what forms.
Exercise 3D Group 7: the halogens
Method. Recall the group.
- Recall. The halogens are group 7.7
- Write the answer. 7
Check. Halogens have 7 outer electrons. ✓
Method. Use the table.
- Look. Chlorine is a green gas at room temperature.green gas
- Write the answer. green
Check. Chlorine is a toxic gas, so it is handled with care. ✓
Method. Use the table.
- Look. Bromine is a red-brown liquid at room temperature.liquid
- Write the answer. liquid
Check. Bromine is the only halogen that is a liquid here. ✓
Method. Use the table.
- Look. Iodine is a grey-black solid at room temperature.solid
- Write the answer. solid
Check. Iodine has the highest melting point of the four. ✓
Method. Melting points increase down group 7.
- Look. Iodine is the lowest halogen in group 7, with the highest melting point.highest
- Write the answer. iodine
Check. Iodine melts at 114 degrees C. ✓
Method. Reactivity decreases down group 7.
- Look. Fluorine is at the top of group 7.top
- Decide. So fluorine is the most reactive.fluorine
- Write the answer. fluorine
Check. Reactivity decreases down the group. ✓
Method. A more reactive halogen displaces a less reactive one.
- Compare. Chlorine is above bromine in group 7.above
- Decide. So chlorine displaces bromide ions.chlorine
- Write the answer. chlorine
Check. Chlorine and potassium bromide give bromine. ✓
Method. Recall the colour of bromine.
- Recall. Bromine is a red-brown liquid, and it forms in the solution.bromine
- Write the answer. bromine
Check. Potassium chloride is the other product. ✓
Method. Compare their positions in group 7.
- Position. Bromine is above iodine in group 7.above
- Decide. So bromine is more reactive.more
- Write the answer. more
Check. Bromine displaces iodide ions. ✓
Method. Compare iodine with chlorine.
- Compare. Iodine is below chlorine, so it is less reactive.less reactive
- Decide. So iodine cannot displace chloride.no
- Write the answer. no
Check. Only the more reactive halogen displaces the other. ✓
Method. Compare bromine with iodine.
- Compare. Bromine is above iodine, so it is more reactive.more reactive
- Decide. So bromine displaces iodine from potassium iodide.yes
- Write the answer. yes
Check. Iodine forms, which is dark. ✓
Method. Chlorine takes the place of bromine.
- Products. Potassium chloride forms, and bromine is displaced.potassium chloride + bromine
- Write the answer. potassium chloride and bromine
Check. Chlorine + potassium bromide -> potassium chloride + bromine. ✓
Method. Think about the hazard.
- Think. Chlorine and bromine are toxic and irritate the lungs and eyes.toxic
- Conclude. So a teacher carries out the reaction in a fume cupboard.teacher
- Write the answer. Accept any sentence that says chlorine is toxic, so pupils must not handle it.
Check. Pupils watch from a safe distance. ✓
Explaining the trends and predicting [H]
Each step down group 1 adds a shell. The outer electron is further from the nucleus, and the inner shells shield it from the attraction of the nucleus, so it is lost more easily. In group 7, each step down adds a shell, so the nucleus is further from the outer shell. An extra electron is attracted less strongly, so the halogens become less reactive down the group.
[H] Higher tier only. Explanation for the trends. In group 1, the outer electron is lost when the atom reacts; a larger atom with more shells loses its outer electron more easily, so reactivity increases down the group. In group 7, the outer shell needs one electron to be full; a larger atom attracts that electron less strongly, so reactivity decreases down the group.
Key ideas
- Group 1: more shells, the outer electron is further from the nucleus and is lost more easily.
- Group 7: more shells, the nucleus attracts an extra electron less strongly, so reactivity decreases.
- The trends are in opposite directions for groups 1 and 7.
- Predictions use the trend; check them with evidence.
Method. Count the shells of each atom.
- Lithium. Lithium is 2,1, which has 2 shells.2 shells
- Potassium. Potassium is 2,8,8,1, which has 4 shells.4 shells
- Decide. Potassium has more shells.potassium
- Write the answer. potassium
Check. Potassium is in period 4. ✓
Method. Compare the number of shells.
- Shells. Astatine is below iodine, so it has one more shell.more shells
- Conclude. A larger atom attracts an extra electron less strongly, so it is less reactive.less reactive
- Write the answer. Astatine has more shells, so the nucleus attracts an extra electron less strongly.
Check. Reactivity decreases down group 7. ✓
Method. Use the trend in group 7.
- Position. Chlorine is above iodine.above
- Decide. Reactivity decreases down the group, so chlorine is more reactive.chlorine
- Write the answer. chlorine
Check. Chlorine is the stronger attractor of an extra electron. ✓
Watch out
Watch out: the trends run in opposite directions. In group 1, reactivity increases down the group; in group 7, it decreases. Do not use the same reason for both.
Exam tip
Exam tip. Link the trend to shells and the outer electron in one sentence: more shells, the outer electron is further away, so it is lost or attracted differently.
Exercise 3E Explaining the trends and predicting
Method. Write the configuration of lithium.
- Configuration. Lithium is 2,1, which has two numbers.2,1
- Count. Two shells.2
- Write the answer. 2
Check. Lithium is in period 2. ✓
Method. Write the configuration of potassium.
- Configuration. Potassium is 2,8,8,1, which has four numbers.2,8,8,1
- Count. Four shells.4
- Write the answer. 4
Check. Potassium is in period 4. ✓
Method. Compare the number of shells.
- Compare. Potassium has 4 shells, and sodium has 3.4 > 3
- Decide. So the outer electron of potassium is further away.potassium
- Write the answer. potassium
Check. More shells means the outer electron is further away. ✓
Method. The outer electron is lost more easily when it is further from the nucleus.
- Compare. Potassium has the most shells of the three.most shells
- Decide. So potassium loses its outer electron most easily.potassium
- Write the answer. potassium
Check. Reactivity increases down group 1. ✓
Method. Think about the shells.
- Shells. Potassium has 4 shells, sodium has 3.4 and 3
- Conclude. The outer electron is further away and more shielded, so it is lost more easily.lost more easily
- Write the answer. Accept any sentence that says the outer electron is further from the nucleus and is more shielded, so it is lost more easily.
Check. Shielding by the inner electrons reduces the pull on the outer electron. ✓
Method. Look at the outer shell.
- Look. Chlorine has 7 outer electrons.7 outer electrons
- Conclude. Gaining one electron fills the outer shell, which is stable.fills the outer shell
- Write the answer. Accept any sentence that says it has 7 outer electrons and gains one to fill its outer shell.
Check. Chlorine is 2,8,7. ✓
Method. Compare the shells.
- Shells. Iodine has 5 shells; chlorine has 3.5 and 3
- Conclude. The nucleus is further from the outer shell, so it attracts an extra electron less strongly.less strongly
- Write the answer. Accept any sentence that says iodine has more shells, so the nucleus attracts an extra electron less strongly.
Check. Reactivity decreases down group 7. ✓
Method. Use the trend down group 7.
- Position. Astatine is below iodine.below
- Decide. Reactivity decreases down the group, so astatine is less reactive.less
- Write the answer. less
Check. Astatine is a prediction; it is radioactive and rarely studied. ✓
Method. Melting points increase down group 7.
- Trend. Iodine is a solid, and astatine is below it.below iodine
- Predict. So astatine is predicted to be a solid.solid
- Write the answer. solid
Check. This is a prediction, not an observation. ✓
Method. Reactivity increases down group 1.
- Position. Caesium is below sodium in group 1.below
- Decide. So caesium is more reactive.caesium
- Write the answer. caesium
Check. Caesium is in period 6. ✓
Method. Think about losing and gaining electrons.
- Group 1. Group 1 atoms lose one electron; this is easier further down.easier
- Group 7. Group 7 atoms gain one electron; this is harder further down.harder
- Conclude. So the two trends run in opposite directions.opposite
- Write the answer. Accept any answer that says group 1 loses an outer electron more easily further down, while group 7 gains one less easily.
Check. Both trends come from the distance of the outer shell from the nucleus. ✓
Chapter summary
| Skill | Method |
|---|---|
| Reactivity series | Potassium (most reactive) to gold (least reactive); metals above copper react with dilute acid. |
| Displacement | A more reactive metal displaces a less reactive metal from its compound (copper sulfate practical). |
| Group 1 with water | Metal + water -> metal hydroxide + hydrogen; reactivity increases down the group. |
| Group 7 properties | Melting points increase down the group; fluorine is a pale yellow gas; iodine is a grey-black solid. |
| Halogen displacement | A more reactive halogen displaces a less reactive halide ion (teacher demonstration). |
| [H] Explanation | Shells and outer electrons decide reactivity; the trends run in opposite directions in groups 1 and 7. |
Can you…?
- I can use the reactivity series to predict whether a displacement happens
- I can carry out the copper sulfate displacement practical safely and record results
- I can describe the reactions of Group 1 metals with water, and the trend down the group
- I can describe the colours, states and melting points of the halogens
- I can write word equations for displacement reactions
- [H] I can explain the trends using electron shells and outer electrons
Key terms
- reactivity series
- the list of metals from most reactive to least reactive
- displacement
- a reaction where a more reactive element takes the place of a less reactive one in a compound
- alkali metal
- a Group 1 metal, such as lithium, sodium or potassium
- hydroxide
- a compound containing OH- ions, such as sodium hydroxide
- halogen
- a Group 7 element, such as chlorine or iodine
- halide ion
- an ion of a halogen, such as chloride (Cl-) or bromide (Br-)
- shielding
- [H] the effect of inner electrons reducing the attraction of the nucleus for outer electrons
Exercise 3Z Check-up
Method. Read the series.
- Read. Zinc, iron, copper are in order.iron
- Write the answer. iron
Check. Iron is more reactive than copper. ✓
Method. Magnesium takes the sulfate.
- Product. Magnesium sulfate forms.magnesium sulfate
- Write the answer. magnesium sulfate
Check. The solution loses its blue colour. ✓
Method. Compare the positions.
- Compare. Magnesium is above copper.above
- Write the answer. magnesium
Check. Magnesium reacts with dilute acid. ✓
Method. Reactivity increases down group 1.
- Compare. Potassium is below lithium.below
- Write the answer. potassium
Check. Potassium is more reactive. ✓
Method. Use the pattern for group 1.
- Products. Sodium hydroxide and hydrogen form.sodium hydroxide + hydrogen
- Write the answer. sodium hydroxide and hydrogen
Check. The solution is alkaline. ✓
Method. Recall the colour.
- Recall. Chlorine is a green gas.green
- Write the answer. green
Check. Chlorine is toxic. ✓
Method. Use the table.
- Look. Bromine is a red-brown liquid.bromine
- Write the answer. bromine
Check. Chlorine is a gas and iodine is a solid. ✓
Method. Compare zinc and magnesium.
- Compare. Magnesium is more reactive than zinc.more reactive
- Decide. So zinc cannot displace magnesium.no
- Write the answer. no
Check. Only the more reactive metal displaces the other. ✓
Method. Chlorine takes the place of bromine.
- Products. Potassium chloride and bromine form.potassium chloride + bromine
- Write the answer. potassium chloride and bromine
Check. Chlorine is more reactive. ✓
Method. Think about shells and attraction.
- Shells. Lower halogens have more shells.more shells
- Conclude. The nucleus attracts an extra electron less strongly, so reactivity is lower.less strongly
- Write the answer. Accept any sentence that says more shells mean the nucleus attracts an extra electron less strongly.
Check. Reactivity decreases down group 7. ✓
Total 24 marks. Allow about 24 minutes.
Exercise 3X Exam-style questions
Method. Use the reactivity series.
- Calcium. Calcium is above zinc.calcium first
- Zinc and copper. Zinc is above copper.zinc, copper
- Write the answer. calcium, zinc, copper
Check. Calcium is higher than zinc in the series. ✓
Method. Think about what happens in the tube.
- Solid. A brown solid forms: copper.brown solid
- Colour. The blue colour of the solution fades.colour fades
- Write the answer. Accept any two of: copper forms, a brown solid, the blue colour fades.
Check. Zinc is more reactive than copper, so a reaction happens. ✓
Method. Recall the product.
- Recall. Metals above copper react with dilute acid to give hydrogen.hydrogen
- Write the answer. hydrogen
Check. Magnesium chloride is the salt. ✓
Method. Use lithium, sodium and potassium.
- Compare. Lithium reacts gently with water, and potassium reacts vigorously.lithium gentle, potassium vigorous
- Trend. So reactivity increases down the group.increases
- Write the answer. Accept any sentence that says reactivity increases down the group.
Check. Potassium is the most reactive of the three. ✓
Method. Use the pattern for group 1 with water.
- Reactants. Sodium and water.sodium + water
- Products. Sodium hydroxide and hydrogen form.sodium hydroxide + hydrogen
- Write the answer. sodium hydroxide and hydrogen
Check. The solution is alkaline. ✓
Method. Use the table of halogens.
- Colour. Bromine is red-brown.red-brown
- State. Bromine is a liquid at room temperature.liquid
- Write the answer. red-brown liquid
Check. Bromine is between chlorine and iodine in its state. ✓
Method. Compare iodine and bromine.
- Compare. Iodine is below bromine in group 7, so it is less reactive.less reactive
- Decide. So iodine cannot displace bromide.no
- Write the answer. no, iodine is less reactive than bromine
Check. Only the more reactive halogen displaces the other. ✓
Method. Think about the chemical.
- Hazard. Chlorine is a toxic gas.toxic
- Conclude. A teacher carries it out in a fume cupboard, so pupils are not at risk.teacher
- Write the answer. Accept any sentence that says chlorine is toxic.
Check. Pupils watch the demonstration from a safe distance. ✓
Method. Think about the reactivity series.
- Name. Copper, silver or gold.copper
- Reason. These are below hydrogen in the reactivity series.below hydrogen
- Conclude. So they do not react with dilute acid.no reaction
- Write the answer. Accept copper, silver or gold, with a reason that they are below hydrogen in the reactivity series.
Check. Metals above hydrogen do react with dilute acid. ✓
Method. Compare the shells.
- Shells. Fluorine has 2 shells; chlorine has 3.2 and 3
- Attraction. Fluorine’s nucleus is closer to the outer shell, so it attracts an extra electron more strongly.more strongly
- Conclude. So fluorine is more reactive.fluorine more reactive
- Write the answer. Accept any answer that says fluorine has fewer shells, so the nucleus attracts an extra electron more strongly.
Check. Reactivity decreases down group 7. ✓