Reactions of acids and making salts
By the end of this chapter you will be able to
- Use universal indicator and the pH scale to classify solutions
- Name a salt from the acid and the metal in it, and write word equations for neutralisation
- Describe each step of making a pure, dry sample of a soluble salt
- Explain the difference between strong and weak acids, and between strength and concentration
- [H] Calculate a concentration from titration results, and write the ionic equation
You should already know
- Ions and charges (Chapter 4)
- Concentration in g/dm3 and moles (Chapters 8 and 9)
Where this leads
- Electrolysis of solutions and products at electrodes (Chapter 11)
- Quantitative analysis of substances (Chapter 17)
GCSE Chemistry. Content follows the GCSE (9-1) subject content for England (Edexcel and AQA). Content references: Use the pH scale and indicators to classify solutions as acidic, neutral or alkaline, Explain acids as sources of H+ ions and alkalis as sources of OH- ions, Describe neutralisation and name the salts made from acids and bases, Carry out the practical to prepare a pure, dry sample of a soluble salt, safely, [H] Write the ionic equation for neutralisation, and use titration to find a concentration.
Exercise P Do you remember?
Method. A hydrogen atom loses its one electron.
- Recall. H+ has one proton and no electrons, so its charge is +1.+1
- Write the answer. +1
Check. The same is true of Na+. ✓
Method. Recall the group.
- Recall. Alkali metals are group 1.1
- Write the answer. 1
Check. Sodium is group 1. ✓
Method. One Cu2+ and one O2-.
- Balance. The +2 and -2 charges balance.CuO
- Write the answer. CuO
Check. Copper oxide is black. ✓
Method. Add the Ar values.
- Add. 2 x 1 + 16 = 18.18
- Write the answer. 18
Check. Water has Mr 18. ✓
Method. Move the decimal point three places to the left.
- Move. 1 divided by 1000 is 0.001.0.001
- Write the answer. 0.001
Check. 1 / 0.001 = 1000. ✓
The pH scale and indicators
The pH scale runs from 0 to 14. Solutions with a pH below 7 are acidic; pH 7 is neutral; solutions above 7 are alkaline. The lower the pH, the more acidic the solution. An indicator changes colour with the pH. Universal indicator shows a range of colours across the whole scale.
| Indicator | In acid | In alkali | Neutral |
|---|---|---|---|
| litmus | red | blue | purple |
| universal indicator | red to orange | blue to violet | green |
Key ideas
- pH below 7: acidic; pH 7: neutral; pH above 7: alkaline.
- Universal indicator shows the pH by its colour, from red (acid) to violet (alkali).
- Litmus is red in acid and blue in alkali.
- pH is measured on a scale; each whole-number step is a tenfold change in H+ concentration.
Method. Find orange on the colour scale.
- Look. Orange is near the acid end of the scale, at about pH 3.pH 3
- Decide. The solution is acidic.acidic
- Write the answer. 3
Check. Red is the strongest acid colour, around pH 1. ✓
Method. Recall what litmus does.
- Recall. Litmus turns blue in alkali.blue in alkali
- Decide. So the solution is alkaline.alkaline
- Write the answer. alkaline
Check. Litmus is red in acid. ✓
Method. Compare the pH values.
- Compare. A lower pH means a more acidic solution.lower
- Decide. So pH 2 is more acidic than pH 5.more
- Write the answer. more
Check. Each pH step is a tenfold change. ✓
Watch out
Watch out: a lower pH means more acidic, not less. Do not read the scale backwards.
Exam tip
Exam tip. When you describe an indicator colour, give the colour and the pH range it suggests.
Exercise 10A The pH scale and indicators
Method. Recall the neutral point.
- Recall. A neutral solution has pH 7.7
- Write the answer. 7
Check. Pure water is neutral. ✓
Method. Compare with 7.
- Compare. pH 3 is below 7.below 7
- Decide. So it is acidic.acidic
- Write the answer. acidic
Check. Lemon juice is around pH 2. ✓
Method. Compare with 7.
- Compare. pH 11 is above 7.above 7
- Decide. So it is alkaline.alkaline
- Write the answer. alkaline
Check. Soapy water is alkaline. ✓
Method. Recall the colour.
- Recall. Litmus is blue in alkali and red in acid.blue
- Write the answer. blue
Check. Litmus is red in acid. ✓
Method. Recall the colour at pH 7.
- Recall. Universal indicator is green at pH 7.green
- Write the answer. green
Check. Green is in the middle of the colour scale. ✓
Method. Compare the colours on the scale.
- Compare. Pink is nearer red than blue on the universal indicator scale.pink nearer red
- Decide. So pink is the more acidic, lower pH.pink
- Write the answer. pink
Check. Red is the most acidic colour. ✓
Method. Recall what neutral means.
- Recall. A neutral solution has equal concentrations of H+ and OH-.equal
- Write the answer. equal
Check. Acids have more H+ than OH-. ✓
Method. Recall the indicator.
- Recall. Universal indicator shows a range of colours across the pH scale.universal indicator
- Write the answer. universal indicator
Check. Litmus only shows acid or alkali. ✓
Method. Red is the most acidic colour.
- Recall. Red corresponds to a pH of about 1.1
- Write the answer. 1
Check. A strong acid has a very low pH. ✓
Method. Violet and purple are alkaline colours.
- Look. Purple is at the high pH end of the scale.high pH
- Decide. So it is alkaline.alkaline
- Write the answer. alkaline
Check. Purple is around pH 13. ✓
Method. Think about the scale.
- Scale. The pH scale is based on the concentration of H+ ions.H+ ions
- Conclude. A lower pH has more H+ ions, so it is more acidic.more H+
- Write the answer. Accept any sentence that says a lower pH means a higher concentration of H+ ions.
Check. Each step of 1 in pH is a tenfold change. ✓
Method. Check the colour.
- Colour. Green is the colour at pH 7.green
- Conclude. So the solution is neutral, not acidic.neutral
- Write the answer. Accept any sentence that says green means pH 7, which is neutral.
Check. Acids turn universal indicator red or orange. ✓
Acids, alkalis and their ions
An acid is a substance that produces H+ ions in aqueous solution. An alkali is a soluble base that produces OH- ions in aqueous solution. The more H+ ions a solution has, the lower its pH. A base is a substance that neutralises an acid; an alkali is a base that dissolves in water.
Key ideas
- Acids produce H+ ions in water.
- Alkalis produce OH- ions in water.
- In neutralisation, H+ and OH- combine to form water: H+ + OH- -> H2O.
- A base is any substance that neutralises an acid; an alkali is a soluble base.
Method. Recall what acids produce.
- Recall. Acids produce hydrogen ions in water.hydrogen ions
- Write. The ion is H+.H+
- Write the answer. H+
Check. H+ is a proton. ✓
Method. Recall what alkalis produce.
- Recall. Alkalis produce hydroxide ions in water.hydroxide ions
- Write. The ion is OH-.OH-
- Write the answer. OH-
Check. OH- has a charge of -1. ✓
Method. H+ and OH- combine to form water.
- Reactants. H+ from the acid and OH- from the alkali.H+ and OH-
- Product. They combine to form water.H2O
- Write the answer. H+ + OH- -> H2O
Check. The charges balance: +1 - 1 = 0. ✓
Watch out
Watch out: an acid is not an acid because it has a lot of water in it. The acid property comes from the H+ ions it releases.
Exam tip
Exam tip. Use the words “H+ ions” and “OH- ions” in your answers about acids and alkalis.
Exercise 10B Acids, alkalis and their ions
Method. Recall the ion.
- Recall. Acids produce H+ ions.H+
- Write the answer. H+
Check. The higher the concentration, the lower the pH. ✓
Method. Recall the ion.
- Recall. Alkalis produce OH- ions.OH-
- Write the answer. OH-
Check. OH- is hydroxide. ✓
Method. Recall the word.
- Recall. A base neutralises an acid.base
- Write the answer. base
Check. Metal oxides and hydroxides are bases. ✓
Method. Recall what an alkali is.
- Recall. An alkali is a base that dissolves in water.yes
- Write the answer. yes
Check. Sodium hydroxide is an alkali. ✓
Method. Recall the product.
- Recall. They combine to form water.H2O
- Write the answer. H2O
Check. Water is neutral. ✓
Method. Recall the ion.
- Recall. The hydroxide ion is OH-.OH-
- Write the answer. OH-
Check. OH is one oxygen and one hydrogen with a -1 charge. ✓
Method. Think about water.
- Look. Water contains a few H+ and OH- ions.both
- Decide. The ion that makes acids acidic is H+.H+
- Write the answer. H+
Check. Only a little water ionises, so pure water is neutral. ✓
Method. Write the ions on the left and the product on the right.
- Left. H+ + OH-.H+ + OH-
- Right. Water is H2O(l).H2O(l)
- Write the answer. H+ + OH- -> H2O(l)
Check. Charges: +1 - 1 = 0 on each side. ✓
Method. Think about the ions.
- Ions. Acids contain free ions in solution.free ions
- Conclude. Moving ions carry the electric current.carry current
- Write the answer. Accept any sentence that says the H+ ions are free to move and carry charge.
Check. Pure water conducts very little. ✓
Method. Think about the ions.
- Ions. An acid gives H+ and an alkali gives OH-.H+ and OH-
- Conclude. They combine to make water, which is neutral.water
- Write the answer. Accept any sentence that says H+ ions and OH- ions combine to form water.
Check. The salt is left in solution. ✓
Method. Link the acid and the ions.
- Acid. More acid gives more H+ ions.more H+
- Conclude. A lower pH, not a higher one, is the result.lower pH
- Write the answer. Accept any sentence that says more acid gives more H+ ions, so the pH is lower.
Check. The pH scale is inverse to H+ concentration. ✓
Neutralisation and making salts
An acid reacts with a base (a metal oxide, a metal hydroxide or a metal carbonate) to form a salt and water. This is neutralisation. Acids also react with some metals to form a salt and hydrogen. The name of the salt has two parts: the metal first, then the acid part (sulfate, chloride or nitrate).
| Base | Word equation with an acid | Gives |
|---|---|---|
| metal oxide | copper oxide + sulfuric acid -> copper sulfate + water | salt and water |
| metal hydroxide | sodium hydroxide + hydrochloric acid -> sodium chloride + water | salt and water |
| metal carbonate | magnesium carbonate + hydrochloric acid -> magnesium chloride + water + carbon dioxide | salt, water and carbon dioxide |
| metal | magnesium + hydrochloric acid -> magnesium chloride + hydrogen | salt and hydrogen |
| Acid | Salt ends with | Example |
|---|---|---|
| sulfuric acid, H2SO4 | sulfate | copper sulfate |
| nitric acid, HNO3 | nitrate | potassium nitrate |
| hydrochloric acid, HCl | chloride | sodium chloride |
Key ideas
- Acid + metal oxide or hydroxide -> salt + water.
- Acid + metal carbonate -> salt + water + carbon dioxide.
- Acid + metal -> salt + hydrogen (metals above copper in the reactivity series).
- Sulfuric acid gives sulfates; hydrochloric acid gives chlorides; nitric acid gives nitrates.
Method. Use the metal and the acid part.
- Metal. The metal is copper.copper
- Acid. Sulfuric acid gives sulfate.sulfate
- Salt. So the salt is copper sulfate.copper sulfate
- Write the answer. copper sulfate
Check. The other products are water. ✓
Method. Neutralisation gives a salt and water.
- Reactants. Hydrochloric acid and sodium hydroxide.acid + alkali
- Products. The salt is sodium chloride, and the other product is water.sodium chloride + water
- Write the answer. sodium chloride and water
Check. The salt is NaCl. ✓
Method. Carbonates give carbon dioxide and water as well as a salt.
- Gas. Carbon dioxide is released.carbon dioxide
- Salt. The salt is magnesium chloride.magnesium chloride
- Write the answer. carbon dioxide, magnesium chloride
Check. Water is also made. ✓
Watch out
Watch out: a salt is not an acid or an alkali. Its name is the metal followed by the acid part, so do not name it “copper acid”.
Exam tip
Exam tip. Write the metal first, then the acid part (sulfate, chloride, nitrate). Check the number of products: salt and water for oxides; salt, water and carbon dioxide for carbonates.
Exercise 10C Neutralisation and making salts
Method. Recall the acid part of the name.
- Recall. Sulfuric acid gives sulfates.sulfate
- Write the answer. sulfate
Check. Copper sulfate and zinc sulfate are examples. ✓
Method. Recall the acid part.
- Recall. Hydrochloric acid gives chlorides.chloride
- Write the answer. chloride
Check. Sodium chloride is common salt. ✓
Method. Recall the acid part.
- Recall. Nitric acid gives nitrates.nitrate
- Write the answer. nitrate
Check. Potassium nitrate is an example. ✓
Method. Metal first, then the acid part.
- Metal. The metal is sodium.sodium
- Acid. Hydrochloric acid gives chloride.chloride
- Write the answer. sodium chloride
Check. Common salt is sodium chloride. ✓
Method. The copper and the sulfate form the salt.
- Salt. Copper oxide and sulfuric acid give copper sulfate.copper sulfate
- Other product. The other product is water.water
- Write the answer. copper sulfate
Check. Copper sulfate is blue. ✓
Method. Recall the products of neutralisation.
- Recall. Neutralisation of a metal oxide gives a salt and water.water
- Write the answer. water
Check. Water has formula H2O. ✓
Method. Recall the gas.
- Recall. Carbonates release carbon dioxide.carbon dioxide
- Write the answer. carbon dioxide
Check. Carbon dioxide turns limewater milky, which is Chapter 17. ✓
Method. Recall the gas from a metal and acid.
- Recall. Metals above copper give hydrogen with dilute acid.hydrogen
- Write the answer. hydrogen
Check. The hydrogen burns with a squeaky pop. ✓
Method. Carbonates make three products.
- Salt. Magnesium chloride.magnesium chloride
- Others. Water and carbon dioxide.water and carbon dioxide
- Write the answer. magnesium chloride, water and carbon dioxide
Check. Three products in total. ✓
Method. The metal and the acid part.
- Metal. Zinc.zinc
- Acid. Nitric acid gives nitrate.nitrate
- Write the answer. zinc nitrate
Check. Zinc nitrate is soluble. ✓
Method. Think about the H+ ions.
- Ions. The H+ ions of the acid are used up in neutralisation.used up
- Conclude. The metal takes their place, forming a salt.takes their place
- Write the answer. Accept any sentence that says the metal replaces the hydrogen ions of the acid.
Check. A salt has the metal in place of the acid’s hydrogen. ✓
Method. Think about the carbonate.
- Carbonate. The carbonate part reacts with the acid.reacts
- Conclude. Carbon dioxide gas is released as the carbonate is used up.carbon dioxide
- Write the answer. Accept any sentence that says the carbonate breaks down to give carbon dioxide.
Check. The gas bubbles off. ✓
Required practical: preparing a pure, dry sample of a soluble salt
To make a pure, dry sample of a soluble salt, use an acid and an insoluble base such as copper oxide. The base is added in excess, so that all the acid is used up. The excess solid is removed by filtration. Then the solution is heated to evaporate some water, and left to crystallise, so crystals of the salt form as it cools. The crystals are dried on filter paper.
Try it (with your teacher). Practical: prepare copper sulfate crystals. Use dilute sulfuric acid and copper oxide only. Wear goggles and gloves, and keep the acid away from your skin and eyes. Warm the acid gently, using a water bath or a low flame under your teacher’s direction. Stop heating before the solution is dry, so that crystals can form as it cools. Do not heat the crystals strongly. Wash your hands when finished. Copper oxide and copper sulfate are harmful: put waste in the labelled container.
Key ideas
- Use an excess of insoluble base so that all the acid is used up.
- Filter to remove the excess solid base.
- Evaporate some of the water, then leave the solution to crystallise.
- Dry the crystals between filter paper; do not heat them strongly.
Method. Think about the acid.
- Look. An excess of solid makes sure all the acid reacts.all acid used
- Conclude. So no acid is left in the salt solution.no acid left
- Write the answer. so that all the acid reacts
Check. The excess solid is removed by filtering. ✓
Method. Think about what is in the mixture.
- Look. The mixture contains the salt solution and the excess solid.solid present
- Conclude. Filtering removes the solid, so only the salt solution passes through.solution passes
- Write the answer. to remove the excess insoluble copper oxide
Check. The filtrate is the salt solution. ✓
Method. Think about the crystals.
- Look. Heating to dryness would give a solid mass, not crystals.dry
- Conclude. Crystals form as the solution cools, so stop when it is nearly saturated.crystals form
- Write the answer. so that crystals form as the solution cools
Check. Saturated means no more salt will dissolve. ✓
Watch out
Watch out: the excess copper oxide is not a mistake. It is there to use up all the acid. Filter it off; do not leave it in the crystals.
Exam tip
Exam tip. Name the four steps in order: excess, filter, evaporate, crystallise and dry. Give one reason for each.
Exercise 10D Required practical: preparing a pure, dry sample of a soluble salt
Method. Recall the first step.
- Recall. Excess copper oxide is added to warm dilute sulfuric acid.excess copper oxide
- Write the answer. add excess copper oxide to dilute sulfuric acid
Check. The excess is removed later. ✓
Method. Recall the process.
- Recall. Filtering separates the insoluble solid from the solution.filtration
- Write the answer. filtration
Check. The filtrate is the salt solution. ✓
Method. Recall the name.
- Recall. The liquid that passes through the filter is the filtrate.filtrate
- Write the answer. filtrate
Check. The solid left on the filter paper is the residue. ✓
Method. Recall the process.
- Recall. Crystals form when the solution is saturated and cools.crystallisation
- Write the answer. crystallisation
Check. Crystals are dried on filter paper. ✓
Method. Recall the colour.
- Recall. Copper sulfate crystals are blue.blue
- Write the answer. blue
Check. Copper sulfate solution is also blue. ✓
Method. Think about the risk.
- Recall. Dilute sulfuric acid can splash into the eyes.eyes
- Write the answer. goggles
Check. Gloves are also needed. ✓
Method. Think about the crystals.
- Look. Crystals of copper sulfate contain water of crystallisation.water
- Conclude. Strong heating removes it and the salt can change.changes
- Write the answer. they would lose water of crystallisation, or decompose
Check. Gentle drying keeps the crystals intact. ✓
Method. Think about the acid in the salt.
- Look. If the acid is not used up, it stays in the solution.stays
- Conclude. Excess base ensures no acid is left in the final salt.no acid left
- Write the answer. to make sure all the acid reacts, so no acid is left in the salt
Check. The excess is filtered off. ✓
Method. Think about the crystals.
- Crystals. Crystals form from a saturated solution as it cools.saturated
- Conclude. Evaporating to dryness would give a solid mass and risk decomposition.decomposition
- Write the answer. Accept any sentence that says crystals form as the solution cools, and drying to dryness may decompose the salt.
Check. Careful evaporation gives crystals. ✓
Method. Think about the order.
- Order. The acid must react with the base first.react first
- Conclude. Only then is the excess solid removed by filtration.then filter
- Write the answer. Accept any sentence that says the copper oxide must react with the acid first, and then the excess solid is filtered off.
Check. Filtering before the reaction would remove the base. ✓
Strong and weak acids, concentration and titration [H]
Strength describes how far an acid ionises (releases H+ ions) in water: a strong acid ionises completely, a weak acid only partly. Concentration is the amount of acid in a given volume. A concentrated weak acid can still be weaker than a dilute strong acid.
In a titration, a solution of known concentration is used to find the concentration of another solution, by finding the volume that just neutralises it. An indicator shows the end point.
[H] Higher tier only. Titration: moles of acid or alkali are found from the concentration and the volume (moles = concentration x volume in dm3). The ratio from the balanced equation then gives the moles of the other reactant, and its concentration = moles / volume (dm3).
| Quantity | Working | Answer |
|---|---|---|
| moles of NaOH | 0.10 x 25.0 / 1000 | 0.0025 mol |
| moles of HCl (1 : 1) | same as NaOH | 0.0025 mol |
| concentration of HCl | 0.0025 / (20.0 / 1000) | 0.125 mol/dm3 |
Key ideas
- Strong acid: ionises completely. Weak acid: ionises only partly.
- Concentration: the amount of acid per volume; strength: how much it ionises.
- Titration uses a known concentration to find an unknown one.
- [H] Use moles = concentration x volume (dm3) and the equation ratio.
Method. Compare strength and concentration.
- Strength. Hydrochloric acid is a strong acid, which ionises completely.strong
- Concentration. A concentrated solution has a lot of acid per volume; ethanoic acid is weak.weak
- Decide. They are different properties, so the answer is no.no
- Write the answer. no
Check. Strength is about ionisation; concentration is about amount. ✓
Method. Find the moles of NaOH, then use the 1 : 1 ratio.
- Moles. moles of NaOH = 0.10 x 25.0 / 1000 = 0.0025 mol.0.0025
- Ratio. NaOH + HCl is 1 : 1, so 0.0025 mol HCl.0.0025 mol
- Concentration. concentration = 0.0025 / (20.0 / 1000) = 0.125 mol/dm3.0.125
- Write the answer. 0.125
Check. 0.125 x 0.0200 = 0.0025 mol. ✓
Method. Recall how titration works.
- Recall. One solution has a known concentration, and it is used to find the unknown one.known
- Decide. So the known concentration is used.known
- Write the answer. known
Check. An indicator shows the end point. ✓
Watch out
Watch out: the acid strength is not the same as its concentration. Do not say a weak acid is “dilute” in place of “weak”.
Exam tip
Exam tip. In a titration calculation, write the moles first, then the ratio, then the concentration. Keep the volume in dm3.
Exercise 10E Strong and weak acids, concentration and titration [H]
Method. Recall the acid.
- Recall. Hydrochloric acid is a strong acid, which ionises completely.strong
- Write the answer. strong
Check. Ethanoic acid is a weak acid. ✓
Method. Recall the acid.
- Recall. Ethanoic acid is a weak acid, which ionises only partly.weak
- Write the answer. weak
Check. Vinegar is ethanoic acid. ✓
Method. Compare strength and concentration.
- Recall. A strong acid can be dilute, so strength and concentration differ.no
- Write the answer. no
Check. Strength is about ionisation. ✓
Method. Recall the definition.
- Recall. Concentration is the amount of solute in a given volume.amount per volume
- Write the answer. the amount of acid per volume
Check. Concentration can be changed by adding water. ✓
Method. Recall the purpose.
- Recall. Titration finds the unknown concentration using a known one.unknown concentration
- Write the answer. to find the concentration of a solution
Check. An indicator shows the end point. ✓
Method. Recall the term.
- Recall. The end point is when the indicator changes colour.end point
- Write the answer. end point
Check. The end point should be the neutral point. ✓
Method. Convert the volume, then multiply.
- Convert. 25.0 / 1000 = 0.025 dm3.0.025
- Multiply. 0.10 x 0.025 = 0.0025 mol.0.0025
- Write the answer. 0.0025
Check. 0.0025 / 0.025 = 0.10 mol/dm3. ✓
Method. The 1 : 1 ratio gives 0.0025 mol HCl; divide by the volume in dm3.
- Ratio. NaOH and HCl react 1 : 1.0.0025
- Divide. 0.0025 / 0.0200 = 0.125.0.125
- Write the answer. 0.125
Check. 0.125 x 0.0200 = 0.0025. ✓
Method. Use the ratio 2 NaOH : 1 H2SO4.
- Ratio. For 1 mol H2SO4, 2 mol NaOH react.2
- Multiply. 2 x 0.0025 = 0.005 mol NaOH.0.005
- Write the answer. 0.005
Check. 2NaOH + H2SO4 -> Na2SO4 + 2H2O. ✓
Method. Convert, then multiply.
- Convert. 25.0 cm3 = 0.025 dm3.0.025
- Multiply. 0.10 x 0.025 = 0.0025.0.0025
- Write the answer. 0.0025
Check. Matches the worked example. ✓
Method. Think about the end point.
- End point. The reaction is complete at a precise point.precise point
- Conclude. The indicator changes colour to show this neutral point.changes colour
- Write the answer. Accept any sentence that says the indicator shows when the acid and alkali are exactly neutralised.
Check. Without it, the end point would be hard to see. ✓
Method. Think about what pH measures.
- Measure. pH measures the H+ ions present in the solution.H+ ions
- Conclude. A weak acid can have a similar H+ concentration to a dilute strong acid.similar
- Write the answer. Accept any sentence that says pH depends on the H+ concentration, not on the acid name.
Check. The details depend on the acid; the principle is the same. ✓
Chapter summary
| Skill | Method |
|---|---|
| pH scale | Below 7 acidic; 7 neutral; above 7 alkaline. Universal indicator shows the scale. |
| Acids and alkalis | Acids give H+ ions; alkalis give OH- ions. |
| Neutralisation | Acid + base -> salt + water; H+ + OH- -> H2O. |
| Salts | Metal first; sulfate, chloride or nitrate depending on the acid. |
| Making a soluble salt | Excess base, filter, evaporate, crystallise, dry. |
| Strength and concentration | Strength = how completely an acid ionises; concentration = amount per volume. |
| [H] Titration | Moles = concentration x volume (dm3); use the ratio, then divide by the volume. |
Can you…?
- I can use the pH scale and indicators to classify solutions
- I can describe acids and alkalis by their ions
- I can write word equations for neutralisation and name the salts
- I can describe each step of making a pure, dry sample of a soluble salt, safely
- I can explain strength and concentration, and describe titration
- [H] I can calculate a concentration from titration results
Key terms
- acid
- a substance that produces H+ ions in aqueous solution
- alkali
- a soluble base that produces OH- ions in aqueous solution
- base
- a substance that neutralises an acid
- neutralisation
- the reaction of an acid with a base to form a salt and water
- salt
- the compound formed when the hydrogen of an acid is replaced by a metal
- indicator
- a substance that changes colour with pH
- titration
- a method of finding the concentration of one solution using another of known concentration
- end point
- the point in a titration where the indicator changes colour
Exercise 10Z Check-up
Method. The metal and the sulfate.
- Name. Zinc and sulfate give zinc sulfate.zinc sulfate
- Write the answer. zinc sulfate
Check. Water is also made. ✓
Method. Recall the gas from carbonates.
- Recall. Carbonates release carbon dioxide.carbon dioxide
- Write the answer. carbon dioxide
Check. Carbon dioxide is tested with limewater. ✓
Method. Recall the neutral point.
- Recall. A neutral solution has pH 7.7
- Write the answer. 7
Check. pH 7 is in the middle of the scale. ✓
Method. Recall the colour.
- Recall. Litmus turns red in acid.red
- Write the answer. red
Check. Litmus is blue in alkali. ✓
Method. The ions combine to form water.
- Product. H+ + OH- -> H2O.H2O
- Write the answer. H2O
Check. Water is neutral. ✓
Method. The metal and the nitrate.
- Name. Potassium and nitrate give potassium nitrate.potassium nitrate
- Write the answer. potassium nitrate
Check. Water is also made. ✓
Method. Think about the solid.
- Look. Copper oxide is insoluble and would contaminate the salt.insoluble
- Write the answer. it is insoluble and is not part of the salt solution
Check. The filtrate is the salt solution. ✓
Method. Recall the first stage.
- Recall. Heating evaporates some of the water, then crystallisation forms the crystals.evaporation
- Write the answer. evaporation
Check. Crystals form as the solution cools. ✓
Method. Divide the moles by the volume.
- Divide. 0.0025 / 0.02 = 0.125.0.125
- Write the answer. 0.125
Check. 0.125 x 0.02 = 0.0025. ✓
Method. Think about what reacts.
- Look. Carbonates react with acid, not with water.with acid
- Conclude. So water alone does not give a reaction in the same way.not water
- Write the answer. Accept any answer that says the acid is needed; water does not neutralise the carbonate.
Check. Acid supplies the H+ ions needed. ✓
Total 20 marks. Allow about 20 minutes.
Exercise 10X Exam-style questions
Method. The metal and the chloride.
- Name. Copper and chloride give copper chloride.copper chloride
- Write the answer. copper chloride
Check. Water is also made. ✓
Method. Neutralisation gives a salt and water.
- Salt. Sodium sulfate.sodium sulfate
- Water. Water.water
- Write the answer. sodium sulfate and water
Check. Water is H2O. ✓
Method. Green is neutral.
- Recall. Green corresponds to pH 7.7
- Write the answer. 7
Check. Neutral solutions are green. ✓
Method. Give the steps in order.
- Step 1. Add excess copper oxide to warm dilute acid.excess copper oxide
- Step 2. Filter off the excess solid.filter
- Step 3. Evaporate some water and leave to crystallise.crystallise
- Write the answer. add excess copper oxide, filter, evaporate and crystallise
Check. Dry the crystals on filter paper. ✓
Method. Think about the acid.
- Acid. If the acid is not all used, it is left in the salt.left in salt
- Conclude. An excess of the solid base makes sure all the acid reacts.all reacts
- Write the answer. Accept any sentence that says it makes sure all the acid reacts.
Check. The excess is then filtered off. ✓
Method. Define each term.
- Strength. Strength is how completely an acid ionises in water.ionises
- Concentration. Concentration is the amount of acid in a given volume.amount per volume
- Write the answer. Accept any answer that says strength is how completely the acid ionises, and concentration is the amount per volume.
Check. A strong acid can be dilute. ✓
Method. Find the moles of NaOH, then use the 1 : 1 ratio.
- Moles. 0.20 x 0.020 = 0.004 mol.0.004
- Ratio. 1 : 1, so 0.004 mol HCl.0.004
- Concentration. 0.004 / 0.025 = 0.160 mol/dm3.0.160
- Write the answer. 0.160
Check. 0.160 x 0.025 = 0.004 mol. ✓
Method. Convert and multiply.
- Convert. 25.0 cm3 = 0.025 dm3.0.025
- Multiply. 0.10 x 0.025 = 0.0025.0.0025
- Write the answer. 0.0025
Check. Matches the worked example. ✓
Method. Recall the process.
- Recall. A titration uses an indicator to find the end point.titration
- Write the answer. titration
Check. Titration finds an unknown concentration. ✓
Method. Think about the products.
- Products. A carbonate gives salt, water and carbon dioxide.carbon dioxide
- Conclude. The carbon dioxide is released as a gas.released
- Write the answer. Accept any sentence that says carbon dioxide is released when the carbonate reacts with the acid.
Check. Carbon dioxide is tested with limewater. ✓